多孔碳的表面改性及电化学储能研究

以孔径为80 nm的大孔有序碳材料（C80）为基体,采用98％ HNO3浸泡氧化改性,研究酸化对多孔碳成分、结构与电化学性能的影响.结果表明：经98％ HNO3氧化改性,多孔碳的孔壁发生膨化,比表面积减小,表面含氮、氧官能团含量增加,进而导致其电化学性能也大幅度地提高;在1 mol/LH2 SO4电解液中,酸化后多孔碳的比电容可达177.6 F/g（电流密度为0.1A/g）,与同一电流密度下的C80相比,比电容提高了50F/g;而以6 mol/L KOH做电解液,比电容提高了36.85 F/g.     

新中国家用电器外功能表面的本土化演变

基于历史文献、实物资料考据,阐述建国后家用电器外功能表面设计本土化的演变过程。通过对家用电器外功能表面材质与装饰的研究,分析建国初期家用电器从无到有、从少到多的演变以及外功能表面设计风格从洋为中用、中西结合,到最终形成独具中国审美、具有时代特色的式样的成因。     

Pedagogy to empower Chinese Learners to adapt to western learning circumstances: a longitudinal case-study

Deficit theorisations of Chinese Learners studying in western countries are criticised for dichotomising learning attributes into Surface- or Deep-learning approaches. Subsequent context-dependent, small culture studies of students transiting between cultures theorise learning as a dynamic journey of adapting to a range/continuum of learning attributes. Here we employ the transformative learning theory to examine whether pedagogical interventions could facilitate adaptation to deeper learning strategies by couching discipline-specific detail/facts within the discipline’s theoretical structure. Our longitudinal case-study of Chinese Learners in an Australian tertiary institution revealed that (1) Achievement-motivated CLs were more likely to harness the benefits of this discipline-specific pedagogical intervention and move towards independent, student-centred learning than Surface-motivated CLs; (2) Achievement-motivated CLs were less likely to normalise teacher-centredness than Surface-motivated CLs despite being exposed to examination tips early in their enrolment; and (3) fluency in the host language is instrumental to adapting successfully to deeper learning.     

Symmetry selective directionality in near-field acoustics

Understanding unidirectional and topological wave phenomena requires the unveiling of intrinsic geometry and symmetry for wave dynamics. This is essential yet challenging for the flexible control of near-field evanescent waves, highly desirable in broad practical scenarios ranging from information communication to energy radiation. However, exploitations of near-field waves are limited by a lack of fundamental understanding about inherent near-field symmetry and directional coupling at sub-wavelengths, especially for longitudinal waves. Here, based on the acoustic wave platform, we show the efficient selective couplings enabled by near-field symmetry properties. Based on the inherent symmetry properties of three geometrically orthogonal vectors in near-field acoustics, we successfully realize acoustic Janus, Huygens, spin sources and quadrupole hybrid sources, respectively. Moreover, we experimentally demonstrate fertile symmetry selective directionality of those evanescent modes, supported by two opposite meta-surfaces. The symmetry properties of the near-field acoustic spin angular momenta are revealed by directly measuring local vectorial fields. Our findings advance the understanding of symmetries in near-field physics, supply feasible approaches for directional couplings, and pave the way for promising acoustic devices in the future.     

Unveiling the molecule–plasmon interactions in surface-enhanced infrared absorption spectroscopy

Nanostructure-based surface-enhanced infrared absorption (SEIRA) spectroscopy has attracted tremendous interest as an ultrasensitive detection tool that supplies chemical-fingerprint information. The interactions between molecular vibrations and plasmons lead to not only the enhancement of spectral intensity, but also the distortion of spectral Lorentzian lineshapes into asymmetric Fano-type or more complicated lineshapes in the SEIRA spectra; this effect hampers the correct readout of vibrational frequencies and intensities for an accurate interpretation of the measured spectra and quantitative analysis. In this work, we investigate the Fano interference between molecular vibrations and plasmons based on exact electrodynamic simulations and theoretical models. We report that, even if the molecular vibrational energy is equal to the plasmon resonant energy, the molecule–nanostructure distance-dependent dipole–dipole interactions, the plasmon-mediated coherent intermolecular interactions and the decay rates of plasmons have a significant impact on the SEIRA lineshapes. This study paves the way for controllable Fano interference at the nanoscale and more studies on plasmon-dressed molecular electronic or vibrational excited states.     

再生水补给河道周边水体特征——以北京潮白河顺义段为例

北京市再生水主要用于河湖补水,但再生水中污染物本底值较高,对周边水体产生了一定影响。本文基于2015—2017年北京潮白河顺义段再生水、地表水和浅层地下水的水位、水质监测数据,运用数理统计和水化学分析等方法,研究了再生水长期补给河道后周边水体的特征。结果表明：①受再生水水质影响,再生水补给河道的地表水总氮在所有监测点均出现超标;河道沿程氮、磷含量降低,pH值升高,夏季更为显著,与藻类光合作用和反硝化作用等因素有关。②周边浅层地下水水位稳定,仅存在季节变化;水化学类型以HCO₃·Cl-Na·Ca型为主,与再生水相似;140个水样中120个符合地下水Ⅳ类及以上标准,沿地下水流向水质有变好趋势;19个水样氨氮超标,主要出现在河南村橡胶坝附近,氮素可能来源于周边农、林地土壤氮素和灌溉施肥输入。③浅层地下水与地表水的主要水化学组分存在差异,与入渗过程中发生阳离子交换吸附作用和混合作用有关;河流渗漏影响到了距离河道中心约425 m的浅层地下水水质。本文可为进一步改善潮白河及其周边地下水水质和提高再生水利用率提供参考。     

粉煤灰粒度分布对水泥性能的影响

利用灰色关联分析方法研究粉煤灰的粒度分布对水泥性能的影响．结果表明：O～5μm、5～10μm粉煤灰颗粒分别是水泥3d、28d抗压强度的最强影响因子;水泥3d、28d强度随小于33μm的粉煤灰颗粒含量增大而提高,随大于33pm的粉煤灰颗粒含量增大而降低;可以通过优化粉煤灰的粒度分布来改善水泥性能．     

基于反向萤火虫算法的多阈值缺陷图像分割(英文)

为了分割QFN表面的缺陷,提出一种基于反向萤火虫算法的大津多阈值分割法.首先,将大津阈值分割扩展为大津多阈值分割.其次,提出了一种基于反向学习的萤火虫算法.在该算法中,生成的反向萤火虫用于增加萤火虫的多样性和全局搜索能力.然后,将基于反向学习的萤火虫算法应用于多阈值分割.最后,使用所提出的方法对QFN缺陷图像进行阈值分割实验,并将结果与穷举法、基于粒子群算法的大津多阈值分割法、基于萤火虫算法的大津多阈值分割法进行比较.实验结果表明,所提方法能更有效地分割QFN表面缺陷,且分割速度快.     

沥青路面除冰雪技术研究(英文)

为降低路面和冰雪之间的黏结力,用有机硅憎水材料作为道路表面涂层.有机硅憎水涂层技术的除冰效果用接触角实验和剪切实验来表征,其耐久性用加速加载磨耗实验来评价,而其抗滑性能则用摆式摩擦法和铺砂法来评价.接触角实验结果表明,有机硅憎水涂层材料与水的接触角为100.2°,具有很好的憎水性能.其次,通过剪切实验可以得出:在涂有有机硅憎水材料的情况下,冰层与试件表面的最大剪切应力仅为0.06 MPa,低于没有进行表面涂层处理的最大剪切力3.5 MPa;剪切之后,冰层能够很完整地从试件表面脱落.加速加载磨耗实验表明,在经过一定时间的磨耗之后,残留在沥青路面构造深度里的有机硅涂层材料仍然具有除冰雪的效果.表面涂层后的道路表面的BPN值和构造深度值均有所降低,但是其仍然远远大于规范的要求,确保了安全性.研究表明,沥青道路表面涂层技术能有效地降低沥青路面与冰层的黏结,从而解决冬季道路结冰影响行车安全的问题.     

Should teachers be accurate or (overly) positive? A competitive test of teacher judgment effects on students’ reading progress

Previous findings on effects of teachers' judgments on student learning have been contradictory leading to the question of what kinds of judgments are most beneficial: accurate or (overly) positive ones? In this study, we provide the first competitive test of prominent but contradictory hypotheses regarding the consequences of teachers' judgments in the context of reading proficiency using reading fluency and reading comprehension performance judgments from 145 teachers and measures of real performance and learning progress across eight points of measurement from 2880 students. Response Surface Analyses combined with an information-theoretic approach for model comparison revealed no evidence of positive effects of judgment accuracy or overestimation of student performance by teachers. Instead, progress in reading fluency and reading comprehension was best predicted by students' prior achievement. For reading comprehension, the positivity of teachers' judgments was additionally beneficial: The higher a teacher judged a student's performance, the more the student learned.