循环伏安法测定染发剂中的对苯二胺

采用循环伏安法,对某品牌染发剂中对苯二胺的含量进行了测定。结果表明,对苯二胺在碳糊电极上产生良好的氧化还原峰,其氧化峰和还原峰峰电位分别为＋0．32V和＋0．24V;反应过程受吸附控制;将该方法用于测定市售染发剂中对苯二胺的含量取得较好的结果。     

山海经、生命智力学与藏羚羊四肢上的氧气囊

帝禹时代的国土资源考察白皮书《山海经.五藏山经》记述有一种尾部有窍口的类似麋鹿的奇异动物＂罴＂,它很可能就是藏羚羊。因为藏羚羊的四肢上部各有一个气囊,后肢气囊的窍口就在尾部。藏羚羊四肢气囊的功能是储存额外的氧气,以供藏羚羊在空气稀薄的青藏高原快速长距离奔跑时对氧气的需求。关于藏羚羊四肢氧气囊的形成原理,达尔文的＂随机微变＋自然选择＂无法解释,而生命智力学暨智因进化论却可以给予充分地解释。目前中国学术界、科学界存在着把批评达尔文、超越达尔文的科学研究视为禁区的潜规则。破除这种潜规则,为中国人的自主原始理论创新开绿灯,有助于中国国家软实力的提高。     

大学有机化学实验教学改革的探索

针对有机实验现有教材的不足,从改革实验教学内容方面对有机化学实验教学进行改革。新的实验分成基本操作实验、多步骤有机合成实验和综合性实验三部分内容,突出完整性、绿色性、实践性的特点。通过教学改革,不但顺利完成教学大纲规定的教学要求,而且全面提高学生的实验操作技术,培养学生的创新能力和科研分析能力。     

A highly alkaline-stable metal oxide@metal–organic framework composite for high-performance electrochemical energy storage

Most metal–organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to alkaline aqueous solutions, thus precluding their use as potential electrode materials for electrochemical energy storage devices. Here, we present the design and synthesis of a highly alkaline-stable metal oxide@MOF composite, Co₃O₄ nanocube@Co-MOF (Co₃O₄@Co-MOF), via a controllable and facile one-pot hydrothermal method under highly alkaline conditions. The obtained composite possesses exceptional alkaline stability, retaining its original structure in 3.0 M KOH for at least 15 days. Benefitting from the exceptional alkaline stability, unique structure, and larger surface area, the Co₃O₄@Co-MOF composite shows a specific capacitance as high as 1020 F g⁻¹ at 0.5 A  g⁻¹ and a high cycling stability with only 3.3% decay after 5000 cycles at 5 A g⁻¹. The as-constructed solid-state flexible device exhibits a maximum energy density of 21.6 mWh cm⁻³.     

Encapsulating metal organic framework into hollow mesoporous carbon sphere as efficient oxygen bifunctional electrocatalyst

Applying metal organic frameworks (MOFs) in electrochemical systems is a currently emerging field owing to the rich metal nodes and highly specific surface area of MOFs. However, the problems for MOFs that need to be solved urgently are poor electrical conductivity and low ion transport. Here we present a facile in situ growth method for the rational synthesis of MOFs@hollow mesoporous carbon spheres (HMCS) yolk–shell-structured hybrid material for the first time. The size of the encapsulated Zeolitic Imidazolate Framework-67 (ZIF-67) is well controlled to 100 nm due to the spatial confinement effect of HMCS, and the electrical conductivity of ZIF-67 is also increased significantly. The ZIF@HMCS-25% hybrid material obtained exhibits a highly efficient oxygen reduction reaction activity with 0.823 V (vs. reversible hydrogen electrode) half-wave potential and an even higher kinetic current density (J_K = 13.8 mA cm⁻²) than commercial Pt/C. ZIF@HMCS-25% also displays excellent oxygen evolution reaction performance and the overpotential of ZIF@HMCS-25% at 10 mA cm⁻² is 407 mV. In addition, ZIF@HMCS-25% is further employed as an air electrode for a rechargeable Zn–air battery, exhibiting a high power density (120.2 mW cm⁻² at 171.4 mA cm⁻²) and long-term charge/discharge stability (80 h at 5 mA cm⁻²). This MOFs@HMCS yolk–shell design provides a versatile method for the application of MOFs as electrocatalysts directly.     

Molecular design revitalizes the low-cost PTV-polymer for highly efficient organic solar cells

Developing photovoltaic materials with simple chemical structures and easy synthesis still remains a major challenge in the industrialization process of organic solar cells (OSCs). Herein, an ester substituted poly(thiophene vinylene) derivative, PTVT-T, was designed and synthesized in very few steps by adopting commercially available raw materials. The ester groups on the thiophene units enable PTVT-T to have a planar and stable conformation. Moreover, PTVT-T presents a wide absorption band and strong aggregation effect in solution, which are the key characteristics needed to realize high performance in non-fullerene-acceptor (NFA)-based OSCs. We then prepared OSCs by blending PTVT-T with three representative fullerene- and NF-based acceptors, PC₇₁BM, IT-4F and BTP-eC9. It was found that PTVT-T can work well with all the acceptors, showing great potential to match new emerging NFAs. Particularly, a remarkable power conversion efficiency of 16.20% is achieved in a PTVT-T:BTP-eC9-based device, which is the highest value among the counterparts based on PTV derivatives. This work demonstrates that PTVT-T shows great potential for the future commercialization of OSCs.     

叶下珠提取方法的研究概况

以国内发表的相关文献为依据,综述了叶下珠提取实验的溶剂选择、提取方法及化学成分的分离和测定方法等方面的研究成果,基于文献中有机溶剂的普遍使用,提出了实验过程应体现绿色化学理念的观点。     

《有机化学》精品课程的建设与实践

本文介绍了在《有机化学》精品课程建设中,如何从建设高素质的教师队伍、编写适合农业院校的教材、结合多媒体技术改革教学方法、建立适合素质教育的考核方法以及有机化学实验教学、独立开课、独立考核、建设精品课程网站、运用先进的网络技术和远程教育来弥补课堂教学的不足等方面,加强教学软硬件建设和改善,对传统有机化学教学进行改革的做法。     

植物酶对有机氧化反应的催化作用的研究

用植物酶对有机氧化反应的催化作用进行研究 ,找出它进行催化时的最适宜温度和最适宜的 PH范围。研究表明 :植物酶能加速有机化合物的氧化 ,植物酶作为催化剂的最适宜温度是5 0℃— 6 0℃ ,最适宜的 PH为 7— 8     

超声波在污水处理中的应用

本文介绍了超声波降解的原理、特点和影响因素以及目前取得的研究成果和主要结论，并对超声降解技术存在的问题和今后的发展趋势进行了讨论．