桥联茂金属催化剂及其性能研究进展

介绍了桥联茂金属催化剂的发展、分类以及它的高立体选择性、高定向性等性能。讨论了桥联茂金属催化剂以及对相关产物立构规整性的影响,并对其应用前景做出展望。     

超声波对醋酸乙烯乳液（VAC）聚合的影响（英文）

对比了醋酸乙烯（VAC）在传统聚合中和超声波辅助聚合中的单体转化率和乳液粒径分布的差别。在VAC聚合过程中外加超声波环境,单体转化率从92.5 %提高到98.8%,乳液粒子平均粒径从136.7nm减小到101.4nm。在超声波辅助VAC乳液聚合中,研究了引发剂浓度和反应温度对单体转化率及乳液粒径分布的影响。试验结果表明仅靠超声波产生的自由基不足以引发聚合反应,引发剂分解产生的自由基在引发聚合过程中起着重要的作用。简单介绍了超声波辅助乳液聚合的机理,超声波可以连续提供自由基,而这些自由基的作用是使死聚合物链变的有活性,导致单体具有较高的转化率。     

THE POLYMERIZATION OF METHYL METHACRYLATE WITH A NEW TIN-BRIDGED YTTROCENE/Al(i-Bu)_3

ＩＮＴＲＯＤＵＣＴＩＯＮＳｉｎｃｅｔｈｅｐｏｌｙｍｅｒｉｚａｔｉｏｎｏｆｍｅｔｈｙｌｍｅｔｈａｃｒｙｌａｔｅ(ＭＭＡ)ｗｉｔｈｒａｒｅｅａｒｔｈｃａｔａｌｙｓｔｓｗａｓｒｅａｌｉｚｅｄｆｏｒｔｈｅｆｉｒｓｔｔｉｍｅｉｎ1991,ａｓｅｒｉｅｓｏｆｎｅｗｒａｒｅｅａｒｔｈｃａｔａｌｙｓｔｓｙｓｔｅｍｓｓｕｃｈａｓＮｄ(Ｐ204)3/Ａｌ(ｉＢｕ)3,Ｎｄ(Ｐ204)3/Ａｌ(ｉＢｕ)3/ＣＣｌ4,Ｎｄ(Ｏｃｔ)3/Ａｌ(ｉＢｕ)3,Ｌｎ(ａｃａｃ)3/ＢｕＭｇＣｌ,Ｙ(ａｃａｃ)3/Ａｌ(ｉＢｕ)3/ＢｕＬｉ,Ｎｄ(ｎａｐｈ)3/ＢｕＬｉ,ａｎｄＮｄ(Ｏ…     

Polymerization of methyl methacrylate with iron-ytterbium dinuclear metallocene catalyst

A novel iron-ytterbium dinuclear catalyst, FcB(MeCp) Yb (MeCp) Cl (Fc: ferrocenyl, B: diethylene ether), was synthesized for the polymerization of methyl methacrylate (MMA). Synergistic effects between the ferrocenyl group and the lanthanocene part were investigated regarding their catalytic behaviors. UV, IR, GPC and NMR were used to characterize the structures of the catalyst and polymer. Kinetic study showed that polymerization is first order in monomer concentration and fractional order (0.78) in the catalyst. The bimetallic complex is a good catalyst for the polymerization of MMA, giving high molecular weight PMMA with 78% syndiotactivity. Project (29774021) supported by NSFC and Laboratory of Rare-Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences     

Modeling for the diffusion limitation of free radical polymerization

A new model was developed to describe the diffusion limitation on free radical polyme-rization. In this model the termination rate coefficient (k _t) and propagation rate coefficient (k _p) were expressed as a function of bulk viscosity (η). This model was used to simulate the batch thermal polymerization of styrene (St) and the continuous thermal bulk copolymerization of St (monomer 1) and maleic anhydride (MAH, monomer 2) in a CSTR with on-line monitor of the rheological behavior. The simulated results on polymerization conversion, copolymer composition, molecular weight and its distributions were compared with the experimental data, and the results calculated by two previous gel-effect models i.e. Martin-Hamielec and Tulig-Tirrell models. It was found that the present model produces better prediction than that of the Tulig-Tirrell model and has the same accuracy as that of the Martin-Hamielec model, but is much simpler. Project (29734130) supported by Natural Science Foundation of China.     

高分子化学悬浮聚合实验教学系统的开发

利用当前通用的多媒体技术、以多媒体制作工具Authorware为主,其它一些主流的媒体创作工具为辅,制作了高分子化学悬浮聚合实验教学系统。它由7个模块组成,即实验目的模块、实验原理模块、实验设备模块、实验步骤模块、实验问题模块、实验设计模块、退出系统模块。它不仅可以作为高分子化学实验教学使用,又便于学生有效地进行实验的预习和复习。该教学系统使用方便、操作简单、针对性强、是一种较实用的计算机辅助教学工具。     

用甲基叔丁基醚为烃化剂合成对叔丁基邻苯二酚的研究

研究了以甲基叔丁基醚为烃化剂合成对叔丁基邻苯二酚。对催化剂的活性,各种副反应及其相应的副产物,投料方式和反应时间等进行了优化考察。当邻苯二酚:甲基叔丁基醚:硫酸=1:1.0:0.1(mol),反应温度110℃,反应时间1.5小时,对叔丁基邻苯二酚的收率达75.7%。     

有机硅改性丙烯酸树脂的制备

有机硅改性丙烯酸树脂(硅丙树脂)的制备方法主要分为物理共混法和化学改性法．综述了近年来关于硅丙树脂制备方面的研究进展，并详细介绍了乙烯基大分子硅单体的制备过程以及硅丙树脂制备过程中乳化体系、单体种类和加料方式等因素对产品性能的影响．     

用于金属腐蚀防护聚苯胺薄膜的研究

聚苯胺作为一种新型的金属腐蚀防护材料,成为当前的一个研究热点.分别用原位聚合法和恒电位法在不锈钢表面合成导电聚苯胺,采用阳极极化曲线和电化学阻抗谱测试等方法研究它对不锈钢在3.5%NaCl溶液中的抗腐蚀能力,并用红外光谱和X射线衍射分析其结构.结果表明,覆有聚苯胺的不锈钢在3.5%NaCl溶液中的自腐蚀电位和极化电阻都明显增大,说明聚苯胺膜的存在明显减慢了不锈钢在氯化钠溶液中的腐蚀速度.     

α，α＇-邻苯二甲基桥联双茚基钐二苯胺化物催化丙烯腈聚合

以α,α＇-邻苯二甲基桥联双茚基钐二苯胺化物为催化剂,对丙烯腈聚合反应进行了研究,考察了催化剂用量、反应时间及反应温度对丙烯腈聚合的影响,并且用粘度法对聚合产物的粘均分子量进行了表征。发现α,α＇-邻苯二甲基桥联双茚基钐二苯胺化物对丙烯腈聚合反应具有极高的催化活性。随着催化剂用量增加聚合反应转化率增大,聚合产物的粘均分子量下降;延长反应时间,转化率和分子量都增大。