TiO2-K2Cr2O7协同光催化氧化体系快速测定染料浓度

基于K2Cr2O2能获得光生电子从而提高半导体光催化氧化能力的原理,建立了一种用纳米Ti02-K2Cr2O2协同体系光催化氧化,分光光度法测定染料浓度的简便方法．探讨了光催化氧化测定染料浓度的机理,考察了染料消解的最佳反应条件．最佳的消解条件为pH=1,TiO21．0g／L,K2Cr2O7初始浓度8．0mmol／L,溶液温度80℃,紫外光照时间10min．当Cl^-含量在1000mg／L以内时,相对误差小于3％．     

三草酸合铁(Ⅲ)酸钾制备实验的改进探索

根据三草酸合铁(Ⅲ)酸钾K3[Fe(C2O4)3].3H2O制备实验的实际情况,对反应温度、H2O2去除时间、Fe(OH)3溶解温度、KHC2O4加入方式进行了探究。通过优化实验过程,可得到粒度较大的翠绿色晶体,提高了产率和实验教学效果。     

Understanding the gum dichromate process in pictorialist photographs: A literature review and technical study

Abstract

In the late 1800s, pictorialist photographers favored a diversity of photographic techniques, including the gum dichromate process. Sometimes superimposed over other photographic images such as platinum and silver prints, the gum dichromate process utilizes a light-sensitive mixture of gum arabic, pigment, and a potassium dichromate solution hand-applied onto a sheet of paper and exposed to light while in direct contact with a negative. The definitive identification of this process has proven to be a challenge due to many variations and intermingling of techniques used by photographers of this period. This research began with a search through the historic literature, followed by the creation of test samples based on historic recipes, and the X-ray fluorescence analysis of these tests. The identification of pigments and the presence of chromium have been associated with the gum dichromate or other dichromated colloid processes in the past. Research results reveal that the presence of chromium may have more complex sources, requiring a more discriminating approach and a modified protocol for the identification of gum dichromate photographs.     

高锰酸钾溶液氧化芳香烃的实验探究

以苯和甲苯为例进行高锰酸钾溶液氧化芳香烃的实验探究,对试样纯度、高锰酸钾溶液及硫酸的浓度、反应温度等影响因素进行了分析,提出了最适宜的实验条件。     

3—环戊氧基雌酮合成方法的改进

采用无水碳酸钾代替乙醇钠与溴代环戊烷和雌酮在无水乙醇中反应，一步制得3－环戊氧基雌酮，利用红外光谱和核磁共振谱对产物进行表征确认，同时探索出最佳反应条件。     

不同类型钾肥对番茄土壤理化性状及微生物的影响

通过番茄土壤对照试验,研究不同类型钾肥对土壤理化性质、微生物及土壤酶活性的影响,结果表明:与对照相比,施用新型含钾中微量元素肥料——"碳酶钾"能够提高番茄土壤有机质、碱解氮、速效磷、速效钾等土壤养分的含量,降低土壤酸度、土壤容重,提高土壤孔隙度,改善了土壤的理化性状;提高了土壤中细菌、真菌、放线菌等微生物的含量;同时还能够显著地增强土壤脲酶、磷酸酶、纤维素酶及过氧化氢酶的活性.     

室温下硫化银的制备及表征

文章采用两种方法合成了Ag2S:以溅射过银的导电玻璃、硫粉和NaOH为反应物,在水中合成了Ag2S;以溅射过银的导电玻璃、硫粉和叔丁醇钾为反应物,在乙醇中合成了Ag2S。采用X射线衍射(XRD)和扫描电子显微镜(SEM)对Ag2S的形貌以及晶体结构进行了表征。结果表明,制备出的Ag2S分别为1μm左右的颗粒和为30nm左右的小颗粒,均为单斜结构。     

氮、磷、钾缺素培养对沙田柚幼苗生长的影响

在室内溶液培养条件下,以沙田柚幼苗为材料,研究了缺N、P、K处理对沙田柚幼苗生长的影响.结果表明:N、P、K缺素处理后沙田柚幼苗的症状出现的时间在28d到43d之间,各种缺素症状出现的部位和表现都不相同.其中缺N处理在培养28d就开始出现全株淡绿色和叶片数少的现象;缺P处理在培养第37d开始出现全株暗绿和叶片数少的现象;而缺K处理在第43d才出现叶片细小钩状,叶缘和叶尖部分出现小坏斑的症状.对沙田柚幼苗嫩老叶叶绿素含量和根的影响最大的都是缺N处理,缺N处理的幼苗老叶和嫩叶叶绿素含量分别只占对照组含量的39.25%和30.18%;生物量受影响程度最大的是缺P处理;新叶生长受影响最大是缺N、P处理后的幼苗,该处理平均只长出了两片新叶.上述不同必需大量矿质元素缺素症的表现特征和规律,可为沙田柚生产中的营养诊断与合理施肥提供依据和指导.     

Characteristics of transient outward potassium channel exposed to 3 mT static magnetic field

Acutely isolated mouse hippocampal CA3 pyramidal neurons were exposed to 3 mT static magnetic field, and the characteristics of transient outward K⁺ channel were studied using the whole-cell patch-clamp technique. The experiment revealed that the amplitude of transient outward potassium channel current was reduced. The maximum activated current densities of control group and exposure group were 163.62±20.68 pA/pF and 98.74±16.57 pA/pF(n=12, P<0.01)respectively. The static magnetic field exposure affected the activation and inactivation process of transient outward potassium channel current. Due to the magnetic field exposure, the halfactivation voltage of the activation curves changed from 5.59±1.96 mV to 27.87±7.24 mV(n=12, P<0.05), and the slope factor changed from 19.43±2.11 mV to 25.87±4.22 mV(n=12, P<0.05). The half-inactivation voltage of the inactivation curves also changed from −56.09±0.89 mV to −57.16±1.10 mV(n=12, P>0.05)and the slope factor of the inactivation curves from 8.69±0.80 mV to 10.87±1.02 mV(n=12, P<0.05). The results show that the static magnetic field can change the characteristics of transient outward K⁺ channel, and affect the physiological functions of neurons.     

2-巯基苯并噻唑三元复合缓蚀剂对碳钢的缓蚀作用

首先研究了2-巯基苯并噻唑（MBT）缓蚀率与其浓度的关系,选用碘化钾（KI）和硫脲（TU）与之进行了三元复配,并通过极化曲线和电化学阻抗研究了三元复合缓蚀剂的缓蚀机理,最后进行了热力学分析。实验结果表明,MBT,KI和TU三元复合缓蚀剂其浓度最佳配比为1：2：2;总浓度为250 mg/L时,在最佳配比下,缓蚀率可达97.7%;三元复合缓蚀剂是以抑制阳极溶解反应为主的混合型缓蚀剂,在碳钢表面的吸附符合Langmuir等温吸附模型。