用稳态近似法推导反应速度方程时应注意的一个问题

用稳态近似法推导反应的速度方程时,最后所导出的速度方程有时会出现由不不同数值而组成的系数。针对这个问题,本文指出了两种避免出现该问题的方法。     

氨氧化法制备丙烯腈反应机理探讨

从有机过渡金属化学理论探讨丙烯氨氧化反应机理     

从认知语言学角度看英汉语时间概念隐喻的差异

英汉语在“时间是空间”、“时间流逝是运动”、“时间是金钱”、“时间是实体”等主要时间概念隐喻及相应的语言表达形式中虽有很多相同之处，但也存在着差异。这些差异来源于英汉不同的认知和社会文化背景。     

Effects of environmental intervention on sedentary time,musculoskeletal comfort and work ability in office workers

Sit–stand workstations offer a potential strategy to reduce prolonged occupational sitting. This controlled intervention study examined the effects of an environmental intervention on occupational sedentary time, musculoskeletal comfort and work ability, and the usability of sit–stand workstations in office work via a self-reported questionnaire. The intervention group (n?=?24) used sit–stand workstations during the 6-month intervention period, and the control group (n?=?21) used traditional sitting workstations. The results showed that working at sit–stand workstations can reduce sitting time significantly compared to control workstations (?6.7% vs. 5.0%, p?=?.019), which is reallocated mostly to standing (r?=??0.719, p?p?=?.028), as well as work ability (p?=?.022). The majority of intervention subjects rated sit–stand workstation adjustability as good (83.3%), and 75.0% were satisfied with the workstation. About 41.7% of the intervention participants, who were exclusively female, used the sit–stand function on a daily basis. While the environmental change alone was effective, it is likely that promoting the daily use of sit–stand workstations with counselling would lead to even more substantial positive effects.     

One hundred and fifty years of sprint and distance running – Past trends and future prospects

Sprint and distance running have experienced remarkable performance improvements over the past century. Attempts to forecast running performances share an almost similarly long history but have relied so far on relatively short data series. Here, we compile a comprehensive set of season-best performances for eight Olympically contested running events. With this data set, we conduct (1) an exponential time series analysis and (2) a power-law experience curve analysis to quantify the rate of past performance improvements and to forecast future performances until the year 2100. We find that the sprint and distance running performances of women and men improve exponentially with time and converge at yearly rates of 4% ± 3% and 2% ± 2%, respectively, towards their asymptotic limits. Running performances can also be modelled with the experience curve approach, yielding learning rates of 3% ± 1% and 6% ± 2% for the women's and men's events, respectively. Long-term trends suggest that: (1) women will continue to run 10–20% slower than men, (2) 9.50 s over 100 m dash may only be broken at the end of this century and (3) several middle- and long-distance records may be broken within the next two to three decades. The prospects of witnessing a sub-2 hour marathon before 2100 remain inconclusive. Our results should be interpreted cautiously as forecasting human behaviour is intrinsically uncertain. The future season-best sprint and distance running performances will continue to scatter around the trends identified here and may yield unexpected improvements of standing world records.     

乙烯式卤代烃亲核取代历程讨论

乙烯式卤代烃难发生亲核取代反应,反应历程研究受到限制.在双键碳中引入超离去基,反应顺利进行,且立体构型发生反转,证明该反应为SN2历程.     

单片机延时方法的分析及应用

单片机开发应用中经常用到延时控制，延时控制的基本方法有纯软件、纯硬件及软硬件结合方法，它们都有各自的特点及应用范围，以1秒延时为例给出用三种方法实现的过程，并介绍了软硬件结合延时的应用实例。     

《文馆词林》残篇二考

文章通过对《文馆词林》所存两篇残敕的文本进行分析,并将其与历史资料对照验证,得出此二敕的作者均为唐太宗,此二敕的写作时间分别为贞观二年(528)正月、三月。     

农村小学英语Story time板块教学常见问题及对策

译林版英语教材中的Story time板块是各个单元的核心板块。教师分析了农村小学英语Story time板块教学存在的几个问题,并针对问题提出了解决策略,以期提高英语教学效率。     

论网络时代高校思想政治工作

网络时代,高校师生的学习方式和生活方式发生了深刻变化。互联网在促进教育发展和人才培养的同时,对学生的消极影响不容忽视。要多方面加强思想政治工作,如开辟网上“思想政治教育课堂”、设置“网上德育阵地”、建立信息监控等。