THE POLYMERIZATION OF METHYL METHACRYLATE WITH A NEW TIN-BRIDGED YTTROCENE/Al(i-Bu)_3

ＩＮＴＲＯＤＵＣＴＩＯＮＳｉｎｃｅｔｈｅｐｏｌｙｍｅｒｉｚａｔｉｏｎｏｆｍｅｔｈｙｌｍｅｔｈａｃｒｙｌａｔｅ(ＭＭＡ)ｗｉｔｈｒａｒｅｅａｒｔｈｃａｔａｌｙｓｔｓｗａｓｒｅａｌｉｚｅｄｆｏｒｔｈｅｆｉｒｓｔｔｉｍｅｉｎ1991,ａｓｅｒｉｅｓｏｆｎｅｗｒａｒｅｅａｒｔｈｃａｔａｌｙｓｔｓｙｓｔｅｍｓｓｕｃｈａｓＮｄ(Ｐ204)3/Ａｌ(ｉＢｕ)3,Ｎｄ(Ｐ204)3/Ａｌ(ｉＢｕ)3/ＣＣｌ4,Ｎｄ(Ｏｃｔ)3/Ａｌ(ｉＢｕ)3,Ｌｎ(ａｃａｃ)3/ＢｕＭｇＣｌ,Ｙ(ａｃａｃ)3/Ａｌ(ｉＢｕ)3/ＢｕＬｉ,Ｎｄ(ｎａｐｈ)3/ＢｕＬｉ,ａｎｄＮｄ(Ｏ…     

Polymerization of methyl methacrylate with iron-ytterbium dinuclear metallocene catalyst

A novel iron-ytterbium dinuclear catalyst, FcB(MeCp) Yb (MeCp) Cl (Fc: ferrocenyl, B: diethylene ether), was synthesized for the polymerization of methyl methacrylate (MMA). Synergistic effects between the ferrocenyl group and the lanthanocene part were investigated regarding their catalytic behaviors. UV, IR, GPC and NMR were used to characterize the structures of the catalyst and polymer. Kinetic study showed that polymerization is first order in monomer concentration and fractional order (0.78) in the catalyst. The bimetallic complex is a good catalyst for the polymerization of MMA, giving high molecular weight PMMA with 78% syndiotactivity. Project (29774021) supported by NSFC and Laboratory of Rare-Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences     

Modeling for the diffusion limitation of free radical polymerization

A new model was developed to describe the diffusion limitation on free radical polyme-rization. In this model the termination rate coefficient (k _t) and propagation rate coefficient (k _p) were expressed as a function of bulk viscosity (η). This model was used to simulate the batch thermal polymerization of styrene (St) and the continuous thermal bulk copolymerization of St (monomer 1) and maleic anhydride (MAH, monomer 2) in a CSTR with on-line monitor of the rheological behavior. The simulated results on polymerization conversion, copolymer composition, molecular weight and its distributions were compared with the experimental data, and the results calculated by two previous gel-effect models i.e. Martin-Hamielec and Tulig-Tirrell models. It was found that the present model produces better prediction than that of the Tulig-Tirrell model and has the same accuracy as that of the Martin-Hamielec model, but is much simpler. Project (29734130) supported by Natural Science Foundation of China.     

怀疑主义的实践可行性问题新探

怀疑主义的重大困难是其实践可行性问题,即怀疑主义者能否在生活中贯彻其怀疑主义。其实,怀疑主义的实践可行性问题的实质就是悬搁判断与信念的相容性,因此,从信念产生的角度是能够解决怀疑主义的实践可行性难题的。     

桥联茂金属催化剂及其性能研究进展

介绍了桥联茂金属催化剂的发展、分类以及它的高立体选择性、高定向性等性能。讨论了桥联茂金属催化剂以及对相关产物立构规整性的影响,并对其应用前景做出展望。     

反兴奋剂工作中的临时停赛规则评述

临时停赛是反兴奋剂工作中较为常见的管理手段，依托反兴奋剂规则体系的建设，临时停赛规则整体上体现出了一致性和灵活性兼备的特点。但由于《世界反兴奋剂条例》临时停赛条款关键内容的缺失，以及各反兴奋剂组织的反兴奋剂规则补充规定的不完善，临时停赛规则的一致性和灵活性相结合的优势未能获得充分发挥，不利于运动员权利的保护，也影响了国际反兴奋剂工作公平协调地进行。完善临时停赛规则应当强调《世界反兴奋剂条例》与各体育组织、反兴奋剂机构的反兴奋剂规则之间的“分工”，并重点关注临时停赛的适用标准、停止条件、违规后果、时长标准和赔偿规则等问题。我国的临时停赛规则存在实践适用较少、认定标准简单的问题，应当借鉴国际经验进一步完善相关规定，助力我国反兴奋剂事业的发展。     

反相悬浮聚合法AA-AM吸水树脂的研究

采用反相悬浮聚合法,以丙烯酸和丙烯酰胺为主要原料,司班60等作为分散剂,环己烷为介质,过硫酸钾-亚硫酸氢钠为引发剂,N,N’-亚甲基双丙烯酰胺为交联剂,合成吸水树脂;考察了防粘剂、分散剂对树脂性能的影响,并对树脂的各种性能进行了分析。实验表明:丙烯酸和丙烯酰胺的单体摩尔比为1∶1.5,水油比为1∶4,引发剂0.7%(质量分数),交联剂0.06%(质量分数),分散稳定剂8%(质量分数),防粘剂PEG-2000和PEG-6000比为1∶1,丙烯酸与氢氧化钠的中和度为75%,反应温度控制在60℃,反应时间为1.5 h,在此条件下,树脂吸水率达870g/g。     

丙烯酸乙酯和丙烯酸丁酯的无皂乳液聚合

实验采用乳化剂中加入甲醇的方法，进行丙烯酸酯的乳液聚合，由于单体的溶解，乳液的稳定性增强，聚合速率增大，而生成的聚合物不溶，从而提高了聚合物胶粒的溶胀能力，使最终的胶粒粒径大大变窄，与常规乳液比较，耐水性及化学稳定性均显著提高。     

Monte Carlo模拟在聚合反应速率常数估算中的运用

1 Introduction It is i mportant to study polymerization mechanisminpolymerization engineering. Obtaining kinetic data isthe key step for establishing polymerization mechanismand understanding elementary reactions . The kineticdata contains two groups of data ,i.e.,the rate andreaction order .The rate ,especially the rate constant ,is i mportant and to be esti mated assuming that the or-der of the reactionis known.Furthermore ,esti mationof rate constants for polymerization is an active anddif…     

贡蕉胚性细胞悬浮培养过程中几个参数的变化

以贡蕉（Musa acuminata cv．Mas）未成熟雄花序来源的胚性愈伤组织为材料建立了贡蕉胚性细胞悬浮系（Embryogenic cell suspensions,ECS）,测定了其培养过程中培养物的鲜重、干重及培养液的PH值、阿拉伯半乳糖蛋白（Arabinogala ctan proteins,AGPs）含量等生长参数在培养过程中的变化动态．结果表明：在培养周期内,培养物的鲜重在继代后第24d达到高峰,干重在继代后第21d达到高峰;培养液中的pH值表现为先下降,第3d下降到最低,随后开始升高;培养液中AGPs含量随培养天数而增加,在第14d含量达到最高,随后保持稳定状态．