使水源中致癌物质降解到微乎其微 高性能降解废水装置让您喝放心水

“虽然我很忌讳用国际先进水平这样的评语，但我还是认为TiO2(二氧化肽)晶须光催化处理难降解有毒有机物废水成套技术及装备研究项目的技术，已经达到国际先进水平。”这是中科院院士陈洪渊在3月8日出席由江苏省环保厅主持的该项目技术鉴定会上说的。     

Microwave-assisted synthesis, anticonvulsant activity and quantum mechanical modelling of N-（4-bromo-3-methylphenyl） semicarbazones

Objective： To study the effect of halo substitution on disubstituted aryl semicarbazones on the anticonvulsant potential and model the activity based on quantum mechanics. Methods： A series of twenty-six compounds of N^4-（4-bromo-3-methylphenyl） semicarbazones were synthesized and evaluated for the anticonvulsant activity in the maximal electroshock seizure （MES） and subcutaneous pentylenetetrazole （scPTZ） seizure threshold tests. Some potential compounds were also tested in the subcutaneous strychnine （scSTY） and subcutaneous picrotoxin （scPIC） seizure threshold tests. The synthesized compounds were tested for behavioral impairment and CNS （central nervous system） depression in mice. Quantum mechanical modelling was carried out on these compounds to gain understanding on the structural features essential for activity. Results： Some compounds possessed broad spectrum anticonvulsant activity as indicated by their effect in pentylenetetrazole, strychnine, picrotoxin and maximal electroshock seizures models in resemblance to other aryl semicarbazone derivatives reported earlier. The higher the difference in HOMO （highest occupied molecular orbital） and LUMO （lowest unoccupied molecular orbital） energy levels was, the greater was the activity profile. Conclusion： The pharmacophoric requirements for compounds to exhibit anticonvulsant activity that includes one aryl unit in proximity to a hydrogen donor-acceptor domain and an electron donor have been justified with the molecular orbital surface analysis of the synthesized compounds.     

夏日传统的最佳饮品——绿豆汤

自从绿豆汤走下神坛,这种传统夏日饮品似乎也受某大师的连累,被人冷落一旁了。其实,绿豆还是那个绿豆,营养保健价值不因为某人的吹嘘而上升,也不因为某人     

纳米碳掺杂TiO2的制备、表征及可见光光催化性能实验

结合科研成果,开设了一种简便的纳米碳掺杂TiO2的制备、表征和可见光光催化性能的实验。实验内容涵盖材料化学、无机合成、仪器分析、催化等专业知识,涉及材料和环境等领域。可作为大学化学综合型实验,也可以此为基础升格为大学化学综合创新型实验。     

镍对小麦幼苗叶片抗氧化酶活性的影响

采用营养液水培,研究了不同浓度（5﹑10﹑20﹑50﹑100、130 mg·L-1）镍处理对小麦幼苗叶片SOD、POD、CAT和APX活性的影响.结果表明,各浓度镍处理均抑制了小麦幼苗叶片SOD活性,而小麦幼苗叶片POD、CAT和APX活性在较低浓度镍处理下升高,在较高浓度镍处理下降低.     

掺杂纳米TiO2光催化研究进展

纳米TiO2因其禁带宽和光生电子与空穴容易复合,而表现出较低的光催化活性,阻止了光催化剂纳米TiO2走向实用化.介绍了利用掺杂与共掺杂、金属与非金属掺杂手段对纳米TiO2进行改性的方法,对进一步扩大纳米TiO2的应用范围,实现纳米TiO2的工业化应用奠定了基础.     

[Bmim]BF4离子液体中微波辅助制备TiO2催化剂及活性研究

采用微波加热合成离子液体[Bmim]BF4,以该离子液体为反应介质,在微波辐射条件下制备TiO2光催化剂,在高压汞灯下用甲基橙溶液测试其光催化降解性能;并用XRD,IR,TG对其进行测试和表征。结果表明,制备TiO2光催化剂的较佳条件是:离子液体2.0mL,微波辐射功率600W、反应温度70℃、反应时间35min。并且用[Bmim]BF4作为反应介质,能够显著提高TiO2的光催化活性,所制备的TiO2不需要经过高温煅烧,就表现出极高的光催化活性。该催化剂对甲基橙的降解率在1.5h就可达到93.7%。