[Cu~(2+)(phen)(SCN~-)_2]_n配合物的合成及晶体结构

以1,10-邻菲咯啉为配体,合成了标题配合物,该化合物的分子式Cu2+(phen)(SCN-)2,分子量359.90,采用经单色化的Mo ka(λ=0.71073)射线测定,共收集3850个衍射点,其中独立衍射点1555个,[Ι>2ó(I)]可观测点数1233个。结果表明该化合物属单斜晶系,C2/c空间群,其晶胞参数:a=1.4067(3)nm,b=1.03281(18)nm,c=1.02975(18)nm,β=111.104(2)o,V=1.3957(4)nm3,z=4,Dc=1.713g.cm-3,μ=1.859 mm-1,F(000)=724,s=1.024,(Δρ)max=0.307e-3和(Δρ)m in=-0.305e-3。该配合物是四配位的平面四边形结构。     

沙田柚果实贮藏期水分变化与枯水的关系

沙田柚采后经预贮10d贮藏于常温室内.用~3H_2O对标记定期测定果蒂部、果皮、果肉(汁胞)的放射性比活度和果实的失重率、果汁率、不同组织含水量、呼吸速率及营养物质含量变化,结果表明,沙田柚贮藏期间,果瓣之间、果肉和果皮之间水分是相互流动的.果实枯水时,水分从果肉到果皮的转移速度大于正常果.沙田柚果实枯水的原因可能是果肉营养物质消耗和果皮组织相对再生长同步进行.     

大气污染对云冈石窟的风化侵蚀及防护对策

云冈石窟地区大气污染较为严重.大气中的污染物主要是SO2、工业粉尘及粉尘中的金属元素,其含量皆严重超标.在有水份的环境中,通过金属离子的催化作用,SO2容易生成H2SO4或酸性物质,再与石质文物表层中CaCO3作用,生成CaSO4*2H2O, 导致风化侵蚀.     

Intellectual property infringements due to R&D abroad? A comparative analysis between firms with international and domestic innovation activities

This paper aims to analyse the risk of intellectual property (IP) infringements by competitors from abroad and in particular to consider whether this risk is higher for international innovating firms. We distinguish three different types of IP infringements from abroad: the usage of firms’ technical inventions, product piracy, and copying of corporate names and designs. Our analysis rests on the German data from the Europe-wide Community Innovation Survey (CIS). We use a unique data set of about 900 observations, which are retrieved from two survey waves. While the earlier wave contains information about international and domestic innovation activities, the later wave reports IP infringements. In a second analysis, the likelihood of infringements from innovation host countries and no-innovation host countries abroad is examined. Before the empirical analysis, an exploratory study was carried out in China with interviews of German firms with innovation activities in China and with a legal advisor for small and medium-sized German enterprises. The results show that firms with international R&D activities are increasing their chances of losing technological knowledge to their local competitors abroad. R&D activities in countries with weak intellectual property rights increase the risk for all types of IP infringements compared to domestic R&D activities. Infringements by competitors from the host country are driven by the production of new produces in this country. Export intensity is the major driver of infringements from no-innovation host countries. R&D activities in China and North America also increase the risk of an infringement. However, firms that innovate only in their home country experience significantly more product piracy cases than international innovating firms.     

水杨醛甲胺磷合铜(Ⅱ)配合物稳定常数测定

用pH法测定了水杨醛甲胺磷席夫碱合铜 (Ⅱ )配合物的稳定常数 ,K =4 .2× 10 14 ,说明该配合物是稳定的。     

组态软件实时数据库系统研究及设计

利用Windows的DLL(动态连接库)和全局共享内存技术来建立系统实时数据库的设计思想,采取传统数据库系统、文件系统和内存数据库系统兼用,利用多种存储介质来构造系统的实时数据库系统,并通过给用户提供一套接口标准——实时数据库系统接口,来实现I/O驱动程序与用户程序和实时数据库系统间的高速数据传递。     

ISBN-10和ISBN-13批量互换算法及程序

主要介绍ISBN-10和ISBN-13之间的差异,给出ISBN-10和ISBN-13之间进行批量互相转换的算法,并在对算法进行分析的基础上,采用VB6.0实现了ISBN-10和ISBN-13批量互换程序。     

十运会男排比赛进攻情况及2008 年北京奥运会备战措施与建议

使用Data Volley软件对十运会男排比赛前八名以及部分现役国家队队员的进攻结构和进攻效果进行了分析,并针对存在的主要问题提出了我国男排备战2008北京奥运会的若干措施与建议：（1）增加专位训练的教练员班子;（2）建立对抗陪练部队;（3）发球的稳定性与攻击性融合;（4）提高远网快球能力;（5）战术组合的重新设计。     

杭州市PM10中有机碳和元素碳变化特征

2001年2月至2002年4月在杭州5个空气质量国控点采集176组PM10样品,分析有机碳（OC）和元素碳（EC）含量,并采用TEOM法同步监测PM10质量浓度,其中在卧龙桥国控点同时测PM2.5质量浓度。全市PM10年日均浓度为119.2mg•m-3。PM2.5年日均浓度为68mg•m-3。PM2.5与PM10质量浓度呈显著的线性关系。PM2.5/ PM10日浓度比值范围在0.31-0.95间变化,平均比值为0.62。OC和EC浓度分别为20.4 mg•m-3和4.0 mg•m-3,其相关性不好表明碳的来源复杂。二次有机碳（SOC）分别占各季OC的 37.1%,45.8%,58.0%,44.7%,表明杭州空气中存在一定的二次有机污染。