铂微粒修饰碳纳米管-纳米TiO2/聚苯胺复合膜电极对抗坏血酸的电催化氧化

采用循环伏安法,在含有0.2mol.L-1苯胺的0.5 mol.L-1的硫酸溶液中,以50mv.s-1的扫描速度,在-0.1~0.9V范围内实现苯胺在碳纳米管-纳米TiO2膜电极上的电化学聚合,得到翠绿色的聚苯胺膜,并用交流阻抗谱对复合膜的电化学性质进行了表征。在该电极上修饰铂,制得铂微粒修饰聚苯胺复合膜电极,研究了其对抗坏血酸的电催化氧化,发现修饰后的电极对抗坏血酸的氧化有很高的催化活性。     

辛二酰氯的合成及其理论计算

以辛二酸为原料,经酰化反应合成得到辛二酰氯,考察了反应时间和反应温度对产物产率的影响,并借助密度泛函量子力学程序对反应前后产物空间结构的变化进行研究.实验结果显示：反应时间24 h,反应温度80℃,辛二酰氯产率为94.7﹪;结构优化后的辛二酰氯HOMO与LUMO轨道上的电子密度下降,且向亚甲基方向偏移.     

山梨酸乙酯的合成研究

以对甲苯磺酸为催化剂,催化合成山梨酸乙酯。考察了原料配比、催化剂的用量、带水剂的用量以及反应时间等条件对反应的影响。实验结果表明,合成山梨酸乙酯的最佳反应条件是：n（山梨酸）：n（乙醇）=1：5,催化剂用量占山梨酸质量的25％,反应时间3h,带水剂用量为15mL,产物收率75．04％,纯度达98％。     

凉州熏醋大曲中细菌区系研究

研究了凉州熏醋传统酿造大曲中细菌区系,对大曲中的细菌总数、醋酸菌、乳酸菌及耐热菌进行计数、分离纯化和鉴定,通过显微镜镜检、革兰氏染色、接触酶反应、需氧型、产酸产气、发酵性等特性测定,对分离的菌株进行了具体菌属鉴定.结果表明,大曲表面与大曲中心细菌区系差异明显;大曲中共分离到5株醋酸菌、8株乳酸菌和4株耐热菌;醋酸菌分属为醋杆菌属和葡糖杆菌属;乳酸菌分属为糖球菌属、链球菌属、魏斯氏菌属、乳球菌属和索丝菌属;耐热菌分属为微球菌属和芽孢杆菌属.     

喙尾琵琶甲流浸膏的镇痛及抗炎作用研究

目的：观察喙尾琵琶甲流浸膏对小鼠的镇痛及抗炎作用。方法：用热板法和醋酸扭体法测定小鼠的痛阈值,二甲苯耳肿胀法测定抗炎作用。结果：喙尾琵琶甲流浸膏高、低剂量组均能提高扭体小鼠痛阈值,高剂量组能显著提高热板实验小鼠痛阈值;喙尾琵琶甲抗炎作用不明显。结论：喙尾琵琶甲流浸膏具有明显的镇痛作用,抗炎作用不明显。     

不同动物肝细胞染色质组分的比较分析

采用BONNER法提取鸡和大白鼠肝细胞染色质的组成成分进行比较分析,结果表明:两者紫外吸收光谱非常相似,在220 nm和260 nm呈现两个吸收峰。鸡肝染色质组成成分DNA∶RNA∶组蛋白∶非组蛋白的质量液度的比值为:1∶0.096∶0.963∶0.53;大白鼠肝细胞染色质组成成分DNA∶RNA∶组蛋白∶非组蛋白的质量液度的比值为:1∶0.077∶1.007∶0.55。     

柴胡种子在萌发过程中氨基酸和蛋白质变化的初步研究

以柴胡种子为材料,经6-BA、60℃、KMnO4和对照4种方法进行萌发处理,测定了萌发处理过程中不同处理时间的柴胡种子中氨基酸和蛋白质含量的变化,初步探讨了在萌发过程中的生理生化变化规律．结果表明：氨基酸的变化总体呈现先升高再降低的趋势．在萌发0-6d之间氨基酸含量迅速升高,6d以后迅速降低,这种变化对柴胡种子的萌发是有利的．在不同处理下,柴胡种子在萌发期间,蛋白质的含量要经历一个迅速升高的过程,这种升高与氨基酸的变化一致．     

Faecal fat content in healthy adults by the ‘acid steatocrit method’

Malabsorption syndromes causing steatorrhoea are quite common in India. Estimation of faecal fat is an important non-invasive investigation, which provides vital information regarding the occurrence of malabsorption. The aim of this study was to estimate the fat excretion per day in stools of apparently healthy adults on an unrestricted diet in random spot stool samples using the Acid Steatocrit Method, which provides an alternate, simpler and yet reliable method of stool fat estimation. Several studies have proved the correlation of the acid steatocrit method with the conventional methods. In India, however, there has been no published data regarding the normal levels of fat in the stools, by the acid steatocrit method. We follow the normal range values, as set by the United States and the European countries, not having a range for the Indian population. Hence, we took up a preliminary study, to estimate stool fat in a section of normal and healthy Indian population. The result obtained after screening 600 healthy and normal adults, showed the mean of stool fat to be 8.72 gms/24 hours, which is much higher than that, defined by Western literature (7 gms/24 hours). This can be accounted for, by the cultural and ethnic variations in dietary and food habits. Further studies are required in the same direction, involving larger population groups, and in different malabsorptive conditions.     

柠檬酸溶胶凝胶法制备铈锆固溶体的物性和氧化还原特性研究

以柠檬酸作为胶凝剂，采用溶胶凝胶法制备了一系列CeXZr1-XO2复合氧化物，分别经600℃和900℃焙烧，应用XRD检测，发现均已形成铈锆固溶体。并应用BET、XRD和TPR对其表相、晶相结构和氧化还原性质进行了分析，发现随着固溶体中铈比例的增加，固溶体稳定性降低；其储氧量测定显示铈锆固溶体用作三效催化剂助剂的最佳比例为1：1。经900℃高温焙烧以后，固溶体晶粒增大不明显，表明本方法适合制备高比表面积和高储氧量的铈锆固溶体；TPR还原峰温度降低，推测可能在于柠檬酸络合物完全分解所致。     

Diagnostic and prognostic value of the urinary excretion of beta-aminoisobutyric acid in patients with urinary bladder cancer

Urinary excretion of beta-aminoisobutyric acid (BAIB), was determined in 28 active and 12 inactive bladder cancer patients. Mean excretion of BAIB was higher in active cancer patients-187.8 mg/24 hours whereas it was 120.4 mg/24 hours in inactive cancer patients. The increased BAIB excretion in both disease groups was independent of tumour stage. BAIB appears to be a useful diagnositic aid in the assessment of bladder cancer patients.