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R.B. Wilsey 《Journal of The Franklin Institute》1925,200(5):673-674
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R.B. Wilsey 《Journal of The Franklin Institute》1922,194(5):583-596
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R.B. Wilsey 《Journal of The Franklin Institute》1925,200(6):739-746
Mixed crystals of silver chloride with silver bromide, and silver bromide with silver iodide, in various proportions of the components, were examined by the X-ray powder method of crystal structure analysis. The AgClAgar mixtures showed the simple cubic structure (NaCl type) characteristic of the pure components, with a lattice spacing lying between those of the two components and following a linear relation with the molecular concentration of each component.Most of the AgBr-AgI. mixtures showed the existence of twoTable II
Mol. per cent. AgCl. | Mol. per cent. AgBr. | Lattice spacing 100 Planes. |
0 | 100 | 2.884 |
20 | 80 | 2.862 |
40 | 60 | 2.840 |
50 | 50 | 2.827 |
60 | 40 | 2.815 |
80 | 20 | 2.794 |
100 | 0 | 2.770 |