电导法测定混合电解质NaCl和KCl水溶液的活度系数

应用电导法测定了盐湖卤水中混合电解质NaCl和KCl水溶液的活度系数,讨论了混合电解质水溶液活度系数随温度和浓度的变化关系.     

利用KCl／Al作为电极的有机电致发光器件

制备了利用KCl／Al作为负电极的有机电致发光器件,器件结构为IT0／NPB／Alq／KCl／Al,KCl层的加入增强了电子注入,当其厚度为1．5nm时,器件的性能最好．与单层Al电极的同类器件相比,此时器件的开启电压由Al电极时的5V降低到了2．5V。器件的亮度在11V时由231cd／m^2提高到15070cd／m^2,器件的发光效率也增加了10倍,达到2．79cd／A．     

Effect of calcium and light on the germination of <Emphasis Type="Italic">Urochondra setulosa</Emphasis> under different salts

Urochondra setulosa （Trin.） C.E. Hubbard is a coastal halophytic grass thriving on the coastal dunes along the Pakistani seashore. This grass could be useful in coastal sand dune stabilization using seawater irrigation. The purpose of this investigation was to test the hypothesis that Ca^2＋ （0.0, 2.5, 5.0, 10.0 and 50.0 mmol/L） alleviates the adverse effects of KC1, MgSO4, NaC1 and Na2SO4 at 0, 200, 400, 600, 800 and 1000 mmol/L on the germination of Urochondra setulosa. Seed germination was inhibited with increase in salt concentration with few seeds germinated at and above 400 mmol/L concentration. No seed germinated in any of the KC1 treatments. Inclusion of CaC12 substantially alleviated the inhibitory effects of all salts. Germination was higher under photoperiod in comparison to those seeds germinated under complete darkness. Among the CaC12 concentrations used, 10 mmol/L was most effective in alleviating salinity effects and allowing few seeds to germinate at 1000 mmol/L KC1, MgSO4, NaC1 and Na2SO4 solution.     

KF-KCl系熔盐的分子动力学模拟

关于KF-KCl系熔盐的混合过程存在较大争议，一种认为混合过程是吸热的，另一种认为混合过程是放热的。文章对KF-KCl系熔盐进行了分子动力学模拟，所得结果与后一种结论一致。并且在实验中观察到了Cl^--Cl^-的偏径向分布函数的第一峰发生了宽达70pm的分裂，这是尚未见于文献的新结果。     

KCl在1,2-丙二醇非水溶剂中热力学性质的研究

应用钾离子选择性电极和Ag-AgCl电极组成可逆电池,通过测定电池的电动势,应用Debye-Hückel极限公式,求得不同温度下KCl在1,2-丙二醇非水溶剂中的活度系数(±),计算了KCl在1,2-丙二醇非水溶剂中的相对偏摩尔自由能(-GB,R),并据电解质溶液的溶剂化理论对KCl的活度系数及相对偏摩尔自由能的变化规律进行了初步的讨论.