生命活性分子与金属离子配合行为的极谱研究——Cu(II)二元配合物(I)

通过脉冲极谱法研究了以生命活性分子(Serine,Cysteine,Salicylic acid等)作为配体与Cu(II)形成多元配合物的极谱行为。在模拟生理条件μ=0.1(NaNO3)、T=310±0.2K下,发现电极过程为准可逆;通过对二元配合物稳定常数的测定表明,不同配体与金属离子配合的能力显著不同,配合物稳定性差异较大;同时还研究了各配合物的形态分布、引起稳定性差异的原因及影响因素。     

三元混配化合物的极谱研究--Phosphonic-、Amino-acid-Eu体系稳定性

以脉冲极谱法研究了用有机磷酸和氨基酸作为配体与Eu(Ⅲ)形成两元及三元体系配合物的极谱行为.模拟生理条件,在μ=O.1(NaCl)、T=310±0.2K条件下,电极过程为准可逆;测定了配合物的稳定常数;讨论了复杂体系各配合物稳定性差异及其影响因素.     

Precision measurement of the Newtonian gravitational constant

The Newtonian gravitational constant G, which is one of the most important fundamental physical constants in nature, plays a significant role in the fields of theoretical physics, geophysics, astrophysics and astronomy. Although G was the first physical constant to be introduced in the history of science, it is considered to be one of the most difficult to measure accurately so far. Over the past two decades, eleven precision measurements of the gravitational constant have been performed, and the latest recommended value for G published by the Committee on Data for Science and Technology (CODATA) is (6.674 08 ± 0.000 31) × 10⁻¹¹ m³ kg⁻¹ s⁻² with a relative uncertainty of 47 parts per million. This uncertainty is the smallest compared with previous CODATA recommended values of G; however, it remains a relatively large uncertainty among other fundamental physical constants. In this paper we briefly review the history of the G measurement, and introduce eleven values of G adopted in CODATA 2014 after 2000 and our latest two values published in 2018 using two independent methods.     

具有分段常数变元的一阶线性微分方程

本文讨论一阶具有分段常数变元线性微分方程的振动性,得到了三个振动性定理。     

均匀外电场中的介质球和椭球的场

本文用球坐标和椭球坐标计算了处于均匀外场中的介质球和介质椭球的场，其内部的场都是与外场方向相同的均匀场．     

具分段常数变元的脉冲微分方程的振动性

研究了一类具有分段常数变元的脉冲时滞微分方程的振动性与非振动性。     

正方介质柱二维光子晶体传输特性FDTD数值研究

把时域有限差分方法用于二维正方介质柱组成光子晶体传输函数理论研究,计算了若干情况下二维光子晶体的透射率即光传输函数随频率的变化。计算结果表明:对于一定的入射方向,某些频率的光不能在光子晶体中传播即出现所谓的禁带,禁带的宽度、频率范围与晶格结构、柱体截面大小及放置方位有关。     

紫外分光光度法测定莽草酸的解离常数

根据光度法测定酸解离常数的原理,采用紫外分光光度法测定了莽草酸的解离常数。在选定波长(215、220、224、226、230 nm)处测定不同pH值的莽草酸溶液吸光度值,得到莽草酸的离解常数为3.87±0.08。方法简便,结果可靠。     

DIELECTRIC STUDIES OF UREASE AS A FUNCTION OF HYDRATION

The steady-state electrical conductivity,as well as the dielectric propertiesbetween 2×10~(-4)Hz and 100 kHz,and at 1 GHz,are reported for urease compressed powdersamples of low hydration.The results show that the large,low frequency dielectricdispersion,known as α-dispersion,is due to the build-up of a space charge of protons atthe sample-electrode interfaces.A smaller dispersion,appearing at higher frequencies,isconcluded to be associated with hindered motions of the peptide residues in the molecularstructure of urease.The extent of these polypeptide backbone motions is shown to bestrongly depended on the extent of enzyme hydration.This work is contributed to the de-velopment of conductimetric biosensors.     

Rate Control for MPEG-4 Bit Stream

Totransmitthemultimediadataovertheinternet ,pre encodedvideobitstreamsarepreferablebecauseofthelimitofthenetworkbandwidth .Inmostcases ,theencodershouldknowthechannelcharacteristicsinad vanceandencodethemasparameters .Consequently ,theflexibilityisreduced .Theratecontrolisemployedtocontroltheoutputbitrateaccordingtonetworkcondi tions.Forwirelessnetworks ,theirbandwidthsaremuchmorelimitedthanwirenetworks.Soratecontrolbecomesespeciallyimportantfortransmittingmultimediaoverthewirelessdomains[1- …