高铁酸钡的电化学合成研究

以2BaO·Fe2O3为正极材料、GP镍氢和镍铬二次商业电池的阴极材料为负极.以13.5 mol·dm-3KOH溶液为电解液,在隔膜电解池中电化学合成高铁酸钡。在合成温度为20℃,电流密度约0.18mA/cm2、电化学合成时间约为50小时的条件下,充电电压为1.45-1.58V,高铁酸钡产率为52.1%。     

EDTA配位滴定法测定热处理盐浴中的氯化钡

研究了用EDTA配位滴定法,结合反滴定方式测定NaCl-BaCl2混合盐中的BaCl2时的相关问题.对照试验的结果表明,该方法测定BaCl2的结果准确、可靠.     

层状复合金属氧化物光催化材料的结构与光谱响应特征

由金属复合氧化物组成的层状材料,包括铌酸盐、钛酸盐、钛铌酸盐等,因其独特的结构和性质使其成为一种新型光催化材料而被广泛研究。通过调节层板组成、结构以及层间离子等可调变其光催化性能,通过插层（柱撑）、剥离组装等可形成丰富的光催化功能材料。本文就该方向的研究做一简要探讨,为进一步构建新型光催化材料提供参考。     

FTIR研究TC—114对环氧树脂固化的催化作用

用FTIR“原位”技术,研究TC—114偶联剂对环氧E—44和二氨基二苯基甲烷(DDM)固化反应的催化作用,得出固化程度与时间的关系曲线.结果表明,催化作用明显.     

Dielectric Properties of ZnTiO3 Microwave Ceramics Consolidated with MgTiO3

STABILIZED ZNTIO, WAS PREPARED BY DOPING MAGNESIUM OXIDE THROUGH TRADITIONAL SOLID-STATE REACTION. THE EXPERIMENTAL RESULTS INDICATE THAT ZINC TITANATE CRYSTALS DOPED WITH MAGNESIUM OXIDE GROW WELL AND THE DECOMPOSITION INTO ZN2TIO4 AND TIO2 IS RESTRAINED THROUGH TRADITIONAL SOLID STATE REACTION. BY ADJUSTING MOLAR RATIO OF MGO, BETTER PROPERTIES CAN BE OBTAINED. THE DIELECTRIC PROPERTIES OF THE CERAMICS DOPED WITH 30% MGO( MOLAR PERCENTAGE) SINTERED AT 1 060 ℃ ARE AS FOLLOWS:THE VALUE OF QUALITY FACTOR IS GREATER THAN 20 000(6. 5 GHZ), THE TEMPERATURE COEFFICIENT OF RESONANCE FREQUENCY IS ABOUT 2 × 10-6/℃, THE DIELECTRIC CONSTANT RANGES FROM 18 TO 22. BESIDES, IT IS PROVED THAT HEAT TREATMENT CAN OPTIMIZE MICROSTRUCTURE AND THE VALUE OF QUALITY FACTOR, WHICH INCREASES FROM 23 833.93 TO 47 584.00 AFTER 2 H OF HEAT TREATMENT AT 1 040 ℃.     

一种测量钛酸钡/聚氨酯材料电致伸缩性能的新方法

提出利用数字散斑相关方法测量材料的电致伸缩性能的新方法.通过数字散斑相关方法得到面内位移,从而由几何三角关系得到离面位移,实现电致伸缩应变的测量.采用该方法对高电场作用下钛酸钡/聚氨酯复合高分子材料的电致伸缩性能进行了测量.在高电场作用下,对重复加电放电过程进行分析,得到电致伸缩应变,从而获取材料的电致伸缩系数.实验中采用双线性插值方法获取亚象素灰度值,以提高测量精度,并将结果与曲面拟合算法的计算结果进行了比较.结果表明:钛酸钡的加入提高了聚氨酯材料的电致伸缩性能;数字散斑相关方法可以有效地实现材料的电致伸缩系数的测量.该方法为电致伸缩性能的研究提供了一种有效的工具.     

Preparation and Characterization of M-Type Barium Ferrite Fibers via Aqueous Sol-Gel Process

BaFe12O19 fibers was prepared via an aqueous sol-gel process using Fe(OH)(HCOO)2 synthesized in laboratory and Ba(CH3COO)2 as the original materials and citrate as the chelate. The rheological behaviour of spinnable sol was characterized on rheometer, and the development of gel fibers to barium ferrite fibers was studied by IR, TG and XRD. Morphology observation of the fibers was given on SEM, and the diameter of the obtained fibers was between 5 and 10 μm corresponding to different additives. The additives affected the surface tension of the precursor sol which had close relation to the microstructure of fibers. Sucrose and hydroxyethylic cellulose could improve the surface tension while diethanolamine and hexadecylamine reduce that of the precursor sol. And using diethanolamine or hexadecylamine as an additive, well-structured BaFe12O19 fibers could be obtained.     

BaTiO3及掺杂镧BaTiO3基超细粉体的制备及表征

以钛酸丁酯、醋酸钡和冰醋酸等为原料,采用溶胶——凝胶法工艺经水解、聚合合成溶胶,之后转变为凝胶,再经充分干燥、煅烧制成BaTiO3及掺杂镧BaTiO3粉体。研究了样品制备过程中影响溶胶——凝胶状态的因素,并用X射线衍射仪对粉体进行测试。实验结果表明:溶胶的初始pH值及温度影响溶胶、凝胶的状态及胶凝化时间,煅烧温度等影响BaTiO3粉体的合成,掺杂镧影响粉体晶粒尺寸的大小。     

植物体内硫含量的测定

通过测定植物叶片中硫的含量可监测空气中SO2的浓度。简述了用氧瓶燃烧——硫酸钡比浊法测定植物叶片中硫含量的实验方法。通过测定标准系列溶液和试样溶液的吸光度,绘制标准曲线,用内插法在标准曲线上求得样品中硫的含量。     

研究钡星重元素丰度的一种模型

提出了一种计算钡星重元素丰度的参数化模型,利用此模型模拟了16颗新观测到的钡星,结果与观测符合,证明了模型的有效性。通过该模型计算出的核合成参数,对相关问题的研究具有重要意义。