二溴羧基偶氮胂催化光度法测定水中痕量锰

研究了在NH_3．H_2O-NH_4Cl 介质中锰催化 H_2O_2氧化二溴羧基偶氮胂褪色的最佳条件。λ_(max)=565nm，表观摩尔吸光系数为2．6×10~4 L·moL~(-1)·cm~(-1)，线性范围为0～2．1 μg/25 mL。用于水样中痕量锰的测定，结果满意。     

Hip and upper extremity kinematics in youth baseball pitchers

The purpose of this study was to examine the relationship between dynamic hip rotational range of motion and upper extremity kinematics during baseball pitching. Thirty-one youth baseball pitchers (10.87 ± 0.92 years; 150.03 ± 5.48 cm; 44.83 ± 8.04 kg) participated. A strong correlation was found between stance hip rotation and scapular upward rotation at maximum shoulder external rotation (r = 0.531, P = 0.002) and at ball release (r = 0.536, P = 0.002). No statistically significant correlations were found between dynamic hip rotational range of motion and passive hip range of motion. Hip range of motion deficits can constrain pelvis rotation and limit energy generation in the lower extremities. Shoulder pathomechanics can then develop as greater responsibility is placed on the shoulder to generate the energy lost from the proximal segments, increasing risk of upper extremity injury. Additionally, it appears that passive seated measurements of hip range of motion may not accurately reflect the dynamic range of motion of the hips through the progression of the pitch cycle.     

木屑制取草酸新法

通过硫酸水解,将木屑中的纤维素转化为葡萄糖,在催化剂作用下,用硝酸将其氧化,制取了草酸.经研究,本法最佳配料比及工艺条件为:干木屑∶硫酸(50%)∶硝酸(65%)∶催化剂=30g∶30mL∶4mL∶0.03g,浸泡水解时间为4h以上,反应时间5h以上,反应温度控制在65～70℃.所得草酸纯度为97.5%,收率达50%.对产品理化数据指标及工艺环保措施进行了分析.     

结晶紫催化动力学光度法测定微量草酸

在稀磷酸介质中,微量草酸对KBrO3氧化结晶紫的褪色反应有显著的活化作用,据此建立了测定微量草酸的新方法。方法的线性范围是O.5-5.0μg/mL,检出限为O.2μg/mL.方法简便,快速,灵敏度高,用于茶叶中草酸含量的测定,结果满意。     

从硫化铜矿制取硫酸铜工艺研究

硫化铜经粉碎，催化焙烧，浸取，铁屑置换制海绵铜，再制取符合GB473－93优等品的硫酸铜产品。     

稀土复合固体超强酸SO_4~(2-)/TiO_2/Ce~(4+)催化合成乙酸环己酯及动力学研究

研究了以稀土复合固体超强酸SO42-/TiO2/Ce4+为催化剂合成乙酸环己酯的反应,在反应温度分别为100℃、110℃、120℃下,测出酯化反应的动力学参数,建立了动力学方程,并与无催化剂作用下合成乙酸环己酯反应的活化能及动力学方程进行了比较.实验结果表明,该催化酯化反应的优化合成条件是:乙酸用量为0.262 1mol时,醇酸摩尔比为1.5:1,催化剂用量为1.0g,带水剂环己烷的加入量为12mL.稀土复合固体超强酸SO42-/TiO2/Ce4+可使反应的活化能明显降低,是合成乙酸环己酯的有效催化剂.     

金属光电效应逸出功简要分析

大学物理教材中对光电效应下的定义不准确,对光电子是否有最大初动能存在两派观点,通过对金属逸出功的分析,表明光电子存在最大初动能。     

汽车尾气催化处理实验研究

以汽车尾气模拟装置中产生的气体作为模拟废气,对于JFG型三元催化剂处理汽车排气中CO、HC和NO的三效性能进行了考察,结果表明该催化剂具有低起燃愠度,良好的冷启动性能和良好的三效性能。同时和HPA-8型催化剂进行了对比,发现HPA-8型催化剂具有优异的控CO和NO的性能。     

Kinematic analysis of the drag flick in field hockey

Attaining high speed of the stick head and consequently of the ball is essential for successful performance of the drag flick in field hockey, but the coordination pattern used to maximise stick head speed is unknown. The kinematics of the drag flick was studied in ten elite hockey players who performed twenty shots each towards a target located 1.5 m high. A 150 Hz active marker motion analysis system was used, alongside two force plates to detect foot touchdown. Angular velocity and contribution to stick endpoint speed of upper body joints were analysed. Repeated measures ANOVA was used to compare timing of onset and peak angular velocities between joints. Participants used a kinematic pattern that was close to a proximal-to-distal sequence. Trunk axial rotation and lateral rotation towards the target, right wrist flexion and left wrist extension were the main contributors to stick endpoint speed. Coaches should emphasise trunk rotations and wrist flexion and extension movements for maximising stick head speed. Given the high level of the participants in this study, the coordination of joints motions, as reported here, can serve as a guideline for drag flick training.     

Effects of changing speed on knee and ankle joint load during walking and running

Joint moments can be used as an indicator of joint loading and have potential application for sports performance and injury prevention. The effects of changing walking and running speeds on joint moments for the different planes of motion still are debatable. Here, we compared knee and ankle moments during walking and running at different speeds. Data were collected from 11 recreational male runners to determine knee and ankle joint moments during different conditions. Conditions include walking at a comfortable speed (self-selected pacing), fast walking (fastest speed possible), slow running (speed corresponding to 30% slower than running) and running (at 4 m · s^?1 ± 10%). A different joint moment pattern was observed between walking and running. We observed a general increase in joint load for sagittal and frontal planes as speed increased, while the effects of speed were not clear in the transverse plane moments. Although differences tend to be more pronounced when gait changed from walking to running, the peak moments, in general, increased when speed increased from comfortable walking to fast walking and from slow running to running mainly in the sagittal and frontal planes. Knee flexion moment was higher in walking than in running due to larger knee extension. Results suggest caution when recommending walking over running in an attempt to reduce knee joint loading. The different effects of speed increments during walking and running should be considered with regard to the prevention of injuries and for rehabilitation purposes.