碳含量对铁基粉末冶金摩擦材料力学性能的影响

随石墨含量增加,铁基粉末冶金含油减磨材料机械性能的变化趋势是密度增加,含油率下降,布氏硬度增加,而压溃强度减小。研究结果表明,石墨含量为1.5wt%和2.0wt%时力学性能较好。     

Phase Transformations of Graphite and Carbon Black by Laser with Low Power Density

The structure phase transformations of graphite and carbon black induced by pulsed laser were studied in this paper.Under irradiation with laser beam of 1.06 μm wavelength and power density of 106 W·cm-2,both graphite structure and carbon black structure were changed obviously.The results of Raman analyses and Transmission Electron Microscopy(TEM)observations show that graphite transforms into nanodiamond about 5 nm and carbon black is graphitized.It is demonstrated that graphite is the intermediate phase in the transformation from carbon black to diamond,and graphite is easier to transform into diamond by laser irradiation than carbon black.     

Experimental and FEM Study of Coated and Uncoated Tools Used for Dry Milling of Compacted Graphite Cast Iron

Compacted graphite cast iron (CGI) has been the material for high-power diesel engines recently, but its increased strength causes poor machinability. In this study, coated and uncoated carbide tools were used in dry milling experiment and FEM simulation to study the machinability of CGI and wear behaviour of tools. The experimental and FEM simulation results show that coated tool has great advantage in dry milling of CGI. SEM and EDS analysis of tool wear indicate the wear morphology and wear mechanism. Adhesive wear is the main mechanism to cause un-coated tool wear, while abrasive wear and delamination wear are the main mechanism to cause coated tool wear. Stress and temperature distribution in FEM simulation help to understand the wear mechanism including the reason for coating peeled off.     

膨胀石墨对二氧化碳的吸附研究

采用常压吸附法研究了膨胀石墨吸附剂在二氧化碳/氮气体系中对二氧化碳的动态吸附性能,比较了其吸附量、穿透曲线和吸附性能的差异.研究了膨胀石墨的比表面积,孔径分布等因素对其二氧化碳吸附性能的影响.结果表明:膨胀体积越大的膨胀石墨,其对二氧化碳的吸附能力越强,最高可达190 mg/g以上.其吸附量随温度升高而呈现下降趋势,但在30℃时吸附量仍达到90 mg/g以上.     

Carbon of Magical Structures

<正>As one of the Partner Groups which were initiated to promote scientifi c exchanges and collaborations between the Max Planck Society(MPS)and the Chinese Academy of Sciences(CAS),the Partner Group led by Prof.Dr.ZHI Linjie was established on May,2010.During the past three years,the group received substantial support from the CAS and the Max-Planck-Institute for Polymer Research(MPIP)for extensive exchanges and collaborations on carbon-rich nanomaterials.Productive collaborations between the researchers and the students from the National Center for Nanoscience and Technology(NCNST)and the MPIP as well as the collaborations between the Partner     

铝合金熔体在线净化系统关键技术创新及应用

通过对引进的铝合金熔体在线净化系统主要参数的研究,优化与改进了净化系统的结构设计,包括反应器、氩气控制系统和石墨转子等核心部件,实现了铝合金熔体在线净化装备的升级创新,其除气除杂效果显著,分别超过40%和85%,铝合金熔体纯净度达到高等级。     

石墨炉原子吸收法测定茶叶中的镍

采用硝酸为介质 ,使用自吸背景校正法 ,测定不同茶叶中的痕量镍并对不同处理方法的结果进行了比较 .该法在 2 0— 40 0 μg/L范围呈良好的线性关系 ,特征量为 4.4× 10 - 1 0 g .     

梭织烧毛机冷水辊筒进水头的改进

织物烧毛是染整工艺中重要的工序,织物运行要求连续不间断,否则会烧坏织物。坯布在冷却时,冷水辊筒进水口存在漏水、使用寿命短、维修困难等问题,从而影响设备正常运行。本文就此问题找出原有设备结构中的不足,提出了改进方案。     

Preparation and characterization of TiO2/expanded graphite

In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high temperature. The samples were analysed by using scanning electron microscope (SEM), X-ray diffraction(XRD), energy disperse spectroscopy(EDS), and differential scanning calorimetry(DSC). The optimal conditions for preparation are as follows: the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1∶0.4, and the calcination and expansion temperature is in the range of 650-750 °C. Under such conditions, the expansion volume of composites could reach 98 mL/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume.     

石墨炉原子吸收直接法测定海水镍和钒

本文研究了海水基体和共存离子对镍和钒的影响,选用酒石酸、乙酸铵分别作为镍和钒的基体改进剂。未加基体改进剂前,海水镍回收率只有77％,钒的测量精度为11％;加人改进剂后均有改善。采用塞曼效应背景校正技术,热解涂层石墨管,建立了石墨炉原子吸收直接测定海水镍和钒的分析方法。镍和钒的特征质量值(mo)分别为8.4pg和17pg;实际检测限:镍为0.25μgL~(-1)和钒为0.41μgL~(-1)。回收率镍为86～110％,钒为88～106％范围。最大相对标准偏差为谋5.5％,钒4.2％。