| 金属多氧络合物引发异丁基乙烯基醚阳离子聚合研究 |
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| 引用本文： | 陈奠宇,陈奠雄. 金属多氧络合物引发异丁基乙烯基醚阳离子聚合研究[J]. 常熟理工学院学报, 2005, 19(6): 40-45 |
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| 作者姓名： | 陈奠宇 陈奠雄 |
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| 作者单位： | 常熟理工学院,化学系,江苏,常熟,215500;陈竹希望学校,四川,眉山,620010 |
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| 摘 要： | 以具有特征Keggin晶体结构的金属多氧络合物——磷钼酸为主要催化剂，以三氯甲烷作溶剂，室温引发异丁基乙烯基醚进行阳离子聚合，考察了特效稳定剂——十六烷基三甲基溴化铵对该反应体系的影响，并系统地比较了不同配比条件下进行阳离子聚合的引发效率。
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| 关 键 词： | 异丁基乙烯基醚 阳离子聚合 金属多氧络合物 |
| 文章编号： | 1008-2794（2005）06-0040-06 |
| 收稿时间： | 2005-10-18 |
| 修稿时间： | 2005-10-18 |
Study of the Cationic Polymerization of Vinyl iso-Butyl Ether (IBVE) Initiated by Polyoxometalatescation |
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| CHEN Dianyu,CHEN Dianxiong. Study of the Cationic Polymerization of Vinyl iso-Butyl Ether (IBVE) Initiated by Polyoxometalatescation[J]. Journal of Changshu Institute of Technology, 2005, 19(6): 40-45 |
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| Authors: | CHEN Dianyu CHEN Dianxiong |
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| Affiliation: | 1. Dept. of Chemistry, Changshu Institute of Technology, Changshu 215500, China; 2. Chenzhu Hoping Middle School ,Meishan 620010, China |
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| Abstract: | In present paper, the polyoxometalate of 12- rnolybdophosphoric acid, with characteristic crystal structure of Keggin,was employed in the system of IBVE cation polymerization.The effect of hexadecyl trimethyl ammonium bromide was studied, and the results showed that cationic polymerization of IBVE was varified with different initiating efficiency. |
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| Keywords: | IBVE cation polymerization polyoxometalate |
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