| 一种Salen双肟类配体及其乙酸铜配合物的合成与表征 |
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| 引用本文： | 冯建华,吴刚,郑建东,侯金松,王俊海.一种Salen双肟类配体及其乙酸铜配合物的合成与表征[J].滁州学院学报,2012,14(2):50-52. |
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| 作者姓名： | 冯建华 吴刚 郑建东 侯金松 王俊海 |
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| 作者单位： | 滁州学院材料与化学工程学院,安徽滁州,239000 |
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| 基金项目： | 安徽省高等学校优秀青年人才基金项目，安徽省教育厅自然科学研究基金项目，安徽省应用化学省级重点学科建设项目 |
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| 摘 要： | 以1,2-二胺氧乙烷和4-羟基水杨醛为原料,在无水乙醇溶剂中合成了Salen双肟类配体5,5′-二羟基-2,2′-乙二氧双(氮次甲基)]二酚(H4L)。以丙酮为溶剂,将H4L与一水合乙酸铜在室温下反应,制备了一种新的Salen双肟类乙酸铜配合物。通过元素分析、核磁共振氢谱、红外光谱、紫外光谱及差热-热重等表征方法得知配合物的可能结构式为Cu(C16H14N2O6)].2H2O。
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| 关 键 词： | Salen双肟类配体 铜(Ⅱ)配合物 合成 表征 |
Synthesis and Characterization of a Salen-type Bisoxime Ligand and its Cupric Acetate Complex |
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| Feng Jianhua,Wu Gang,Zheng Jiandong,Hou Jinsong,Wang Junhai.Synthesis and Characterization of a Salen-type Bisoxime Ligand and its Cupric Acetate Complex[J].Journal of Chuzhou University,2012,14(2):50-52. |
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| Authors: | Feng Jianhua Wu Gang Zheng Jiandong Hou Jinsong Wang Junhai |
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| Institution: | Feng Jianhua,Wu Gang,Zheng Jiandong,Hou Jinsong,Wang Junhai |
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| Abstract: | A Salen-type bisoxime ligand 5,5’-Dihydroxy-2,2’ethylenedioxybis(nitrilomethylidyne)] diphenol(H4L) was synthesized in anhydrous ethanol solvent by the means of 1,2-bis(aminooxy) ethane with 2,4-dihydroxybenzaldehyde.A novel Salen-type bisoxime cupric acetate complex was also synthesized in acetone by the reaction of H4L and copper(Ⅱ) acetate monohydrate at room temperature.The compounds were characterized by elemental analysis、1H NMR、IR、UV and TG-DTA.The results indicated that the structural formula of the complex was suggested asCu(C16H14N2O6)]·2H2O. |
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| Keywords: | Salen--type bisoxime ligand Cu(II) complex synthesis characterization |
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