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烯烃的折光指数与密度之间定量关系的研究
引用本文:王克强,吴立文. 烯烃的折光指数与密度之间定量关系的研究[J]. 商丘师范学院学报, 1998, 0(Z4)
作者姓名:王克强  吴立文
作者单位:华东理工大学化学系!上海,200237(王克强),信阳县王岗中学!信阳,464146(吴立文)
基金项目:河南省优秀青年骨干教师资助
摘    要:根据分子结构的特,发和分子性能的结构基础,探讨了烯烃的密度与折光指数之间的定量关系,发现烯烃的密度与折光指数的平方呈良好的线性关系,据此发展了一种密度和折光指数的相互预测方法(用折光指数预测密度或根据密度预测折光指数).对203种烯烃的计算结果表明,预测值与实验值的一致性令人满意,对密度和折光指数和预测结果的平均误差分别为0.43%和0.15%.

关 键 词:烯烃  折光指数  密度  计算方法

STUDIES ON THE QUANTITATIVE RELATIONSHIP BETWEEN DENSITIES AND REFRACTIVE INDEXES OF ALKENES
Wang Keqiang,Wu Liwen. STUDIES ON THE QUANTITATIVE RELATIONSHIP BETWEEN DENSITIES AND REFRACTIVE INDEXES OF ALKENES[J]. Journal of Shangqiu Teachers College, 1998, 0(Z4)
Authors:Wang Keqiang  Wu Liwen
Abstract:Based on the characteristics of molecular structure and structural basis of molecular property, the quantitative relation between dens1ty and refractlve index of alkenes was studied and an equation with only one constant was proposed to predict the refractive indexes from the densities or to predict the densities from the refractive indexes of alkenes. The results showed that the predicted values of densities and refractive indexes were in good agreement with the experimental data,and the mean relative deviations were 0. 43% and O. 15%for density and refractive index respectively.
Keywords:alkene density  refractive index  quantitative relation  predicting method
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