| 膨胀阻燃聚丙烯燃烧残炭的结构分析 |
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| 引用本文： | 梁敏仪,黄秋芬,刘祥军,冯才敏.膨胀阻燃聚丙烯燃烧残炭的结构分析[J].顺德职业技术学院学报,2014(3):12-14. |
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| 作者姓名： | 梁敏仪 黄秋芬 刘祥军 冯才敏 |
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| 作者单位： | 顺德职业技术学院应用化工技术学院,广东佛山528333 |
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| 基金项目： | 顺德区科技计划项目（20130202030）. |
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| 摘 要： | 采用离子色谱法测定残炭提取液中离子及其含量，并用红外光谱仪和x-荧光光谱法（EDX）分析了残炭在浸泡前后的结构变化。结果表明，在超纯水中浸泡得到磷酸根离子；在80℃温度下，震荡提取72小时后，提取液中磷酸根离子浓度达到最大值；提取后残炭中磷含量显下降，P-O-P和P-O-C结构的吸收峰显著减小。说明，残炭中大部分的P-O-P和P-O-c键水解成磷酸根，残留的P可能进入残炭的环状结构或与环状结构直接相连。
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| 关 键 词： | 残炭 残炭结构 磷含量 |
Char Chemical Structure Analysis of Intumescent Flame Retardant Polypropylene after Burning |
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| Authors: | LIANG Minyi HUANG Qiufen LIU Xiangjun FENG Caimin |
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| Institution: | (College of Applied Chemical Engineering, Shunde Polytechnic, Foshan Guangdong 528333, China) |
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| Abstract: | The kind and content of anion in the char was determinated by ion chromatography, and the structure was characterized by Fourier Transform infrared spectroscopy （FTIR） and X-ray Fluorescence Spectrometer （EDX）. The re- suits showed that phosPhate group was detected in the solution; when the temperature was 80 ℃ and the soak time was 72 hours, the value of phosphate group in the solution reach the maximum; the P content decreased with the decrease of P-O-P and P-O-C absorption strength, which revealed that P-O-P and P-O-C bond were hydrolysed to phosphate group, and the residual P entered polyaromatic ring or connected to polyaromatic ring directlt. |
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| Keywords: | char residue structure of char residue P content |
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