| 5-氯-6-羟基吡啶甲酸三苯基锡酸酯的合成和晶体结构 |
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| 引用本文： | 翟秀荣.5-氯-6-羟基吡啶甲酸三苯基锡酸酯的合成和晶体结构[J].济宁师范专科学校学报,2014(3):18-20. |
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| 作者姓名： | 翟秀荣 |
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| 作者单位： | 济宁学院化学与化工系,山东曲阜273155 |
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| 基金项目： | 山东省高校科研计划项目（J13LD58）;济宁市科技发展（社会与民生）计划项目（20125014）;济宁学院青年科研基金项目（2011QNKJ03） |
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| 摘 要： | 由1:1的三苯基氢氧化锡和5-氯-6-羟基吡啶甲酸反应得到5-氯-6-羟基吡啶甲酸三苯基锡酸酯.在此化合物的结构中,锡原子与三个苯基碳原子和两个氧原子相结合,一个氧原子来自羧基,另一个来自酚羟基,呈五配位变形的三角双锥结构,酚羟基氧原子与其相邻的锡原子键合形成一维链状结构.
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| 关 键 词： | 合成 -氯--羟基吡啶甲酸 晶体结构 |
Synthesis and Crystal Structure of Triphenyltin Ester of 5-Chloro-6- hydroxynicotinic Acid |
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| ZHAI Xiurong.Synthesis and Crystal Structure of Triphenyltin Ester of 5-Chloro-6- hydroxynicotinic Acid[J].Journal of Jining Teachers College,2014(3):18-20. |
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| Authors: | ZHAI Xiurong |
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| Institution: | ZHAI Xiurong (Department of Chemistry and Chemical Engineering, Jining University, Qufu 273155, China) |
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| Abstract: | A novel organotin compound Ph3Sn（OCOC5H2N-3-Cl-5-O-6）]. has been synthesized by the reaction of tripnenyltin hydroxide with pyridine-3-earboxylic acid in 1：1 ratio The molecular structure presents five-coordinated trigonal bipyramidal structure because the tin atom is combined with three phenyl carbon atoms and two oxygen atoms which are respectively from carboxylate and phenolic hydroxide. A one-dimensional linear polymer is formed by the interaction between the O atom of phenolic hydroxide and the adjacent tin atom. |
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| Keywords: | synthesis 5-cholorlo-6-hydroxynicotinic acid crystal strucrure |
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