Maximum temperature in fixed-bed sorption columns and isosteric heats of adsorption

Heat effects in fixed-bed sorption columns are often quite large and have a pronounced effect on the sorption kinetics. Proper design of such systems must include consideration of these effects.A method is developed for computing the maximum possible bed temperature. The model is tested on two systems: (1) the Linde molecular sieve 4 A/water system and (2) the Alcoa activated alumina F-1/water system. Since the predicted temperatures appeared to be low for the latter system, the model was refined by the inclusion of the isosteric integral heat of adsorption. Tests on the activated alumina show considerable improvement.The isosteres of two sorption therm correlations are investigated. The results show that the heat of adsorption of water on the alumina varies logarithmically with sorbate concentration—approaching high values at low concentrations and approaching the heat of vaporization of water at high concentrations. The results also suggest that the isosteric heat of adsorption behavior may be of use in assessing the “goodness of fit” of sorption therm correlations.