| CaF2-doped ZrO2： A base catalyst for synthesis of dimethyl carbonate |
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| 引用本文： | 王慧,时森,王瑶,李长顺,孙俭. CaF2-doped ZrO2： A base catalyst for synthesis of dimethyl carbonate[J]. 上海大学学报(英文版), 2010, 14(4): 281-285. DOI: 10.1007/s11741-010-0644-1 |
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| 作者姓名： | 王慧 时森 王瑶 李长顺 孙俭 |
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| 作者单位： | School of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,P.R.China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (Grant No.10271074) |
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| 摘 要： | The effect of CaF2-doped ZrO2 catalyst for the synthesis of dimethyl carbonate （DMC） was studied by X-ray diffraction （XRD）, CO2-temperature programmed desorption （TPD）, Raman spectra, and X-ray photoelectron spectroscopy （XPS）. Catalytic performance was evaluated in the bath and distillation reactors. Results showed that the CaF2/ZrO2 catalysts had activity and stability for DMC synthesis.
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| 关 键 词： | 碳酸二甲酯 锆催化剂 氧化锆 钙掺杂 合成 氟化 X射线光电子能谱 X射线衍射仪 |
| 收稿时间： | 2009-11-25 |
| 修稿时间： | 2010-01-11 |
CaF2-doped ZrO2: A base catalyst for synthesis of dimethyl carbonate |
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| Hui Wang,Sen Shi,Yao Wang,Chang-shun Li,Jian Sun. CaF2-doped ZrO2: A base catalyst for synthesis of dimethyl carbonate[J]. Journal of Shanghai University(English Edition), 2010, 14(4): 281-285. DOI: 10.1007/s11741-010-0644-1 |
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| Authors: | Hui Wang Sen Shi Yao Wang Chang-shun Li Jian Sun |
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| Affiliation: | School of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,P.R.China |
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| Abstract: | The effect of CaF2-doped ZrO2 catalyst for the synthesis of dimethyl carbonate(DMC)was studied by X-ray diffraction(XRD),CO2-temperature programmed desorption(TPD),Raman spectra,and X-ray photoelectron spectroscopy(XPS).Catalytic performance was evaluated in the bath and distillation reactors.Results showed that the CaF2/ZrO2 catalysts had activity and stability for DMC synthesis. |
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| Keywords: | CaF2 ZrO2 dimethyl carbonate(DMC) |
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