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Catalytic Effect of SCN^— on Electrodeposition of Zinc—Nickle Alloy
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关 键 词:锌-镍合金  反常沉积  结晶效应
收稿时间:15 June 2000

Catalytic effect of SCN? on electrodeposition of zinc-nickle alloy
Authors:Zheng-hua Fang  Ren-he Yin  A Zakaria  Li Zhang
Institution:(1) Department of Chemistry, College of Science, Shanghai University, 200436 Shanghai, China
Abstract:The electrodeposition of zinc-nickle alloy was obtained on a copper cathode of 1×1cm2. The deposited alloys are quantitatively analyzed by atomic absorption spectrometry. The morphology of the deposits was observed by means of scanning electron microscopy (SEM). We observed that the electrodeposition of zinc-nickle alloy is an anomalous codeposition. The catalytic effects of SCN” on the electrochemical behavior of Ni deposition and hydrogen discharge are obvious. SEM analysis shows that the surface morphology of the coating appears to be more compact and homogeneous with the increase of SCN” concentration. Supported by the State Key Lab. for Phys. Chem. of Solid Surface, Xiamen University
Keywords:zinc-nickle alloy  anomalous codeposition  catalytic effect
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