| Fe/Ce-HMS纳米中孔材料的原位合成 |
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| 引用本文： | 陈君华,陈庆榆,戚邦华,黄顺军,伏再辉. Fe/Ce-HMS纳米中孔材料的原位合成[J]. 安徽科技学院学报, 2003, 17(4): 330-332 |
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| 作者姓名： | 陈君华 陈庆榆 戚邦华 黄顺军 伏再辉 |
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| 作者单位： | 1. 安徽技术师范学院,基础部,安徽,凤阳,233100
2. 湖南师范大学,化学化工学院,湖南,长沙,410081 |
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| 基金项目： | 安徽省教育厅自然科学基金;2001kj059; |
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| 摘 要： | 合成含双元或多元金属的中孔载体材料,以期得到稳定高效多用途的工业催化剂,是材料研究方面新的趋势。采用中性伯胺(DDA)模板剂,在硅酸四乙酯(TEOS)的水解聚沉过程中,将双元金属Fe、Ce引入中孔分子筛骨架中,首次原位合成了分子自组装Fe/Ce-HMS。低角X衍射(XRD)、电子衍射(ED)及电镜(HTEM)分析表明合成样品为一维直通道纳米中孔材料,同时傅立叶红外变换(FT-IR)光谱分析发现SO_4~(2-)有强化分子的组装作用。
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| 关 键 词： | HMS 纳米材料 合成 表征 组装 |
| 文章编号： | 1672-3589(2003)04-0330-03 |
| 修稿时间： | 2003-05-16 |
In Situ Synthesis of Nano-material on Iron and Cerium-containing Hexagonal Mesoporous Silica Sieve |
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| CHEN Jun-hua,CHEN Qing-yu,QI Bang-hua,HUANG Shun-jun,FU Zai-hui. In Situ Synthesis of Nano-material on Iron and Cerium-containing Hexagonal Mesoporous Silica Sieve[J]. Journal of Anhui Science and Technology University, 2003, 17(4): 330-332 |
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| Authors: | CHEN Jun-hua CHEN Qing-yu QI Bang-hua HUANG Shun-jun FU Zai-hui |
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| Abstract: | To development a stable highly effective multi - functional catalyst with two or more metal elements-containing hexagonal mosoprous silica sieve(HMS) is newly a heat point in the filed of material. At present, iron and cerium-containing HMS by molecular assembly in themselves with the template reagent of dodecyl amine in the course of the hydrolytic coagulation of ethyl silicate(TEOS) was primarily prepared. Characterized by X - ray diffraction(XRD) ,fourier transform infrared spectrometer (FT-IR), high-resolution electron microscope( HTEM) etc, the structure of sample with one dimension direct channel was shown, elements of iron and cerium were located in seats of lattice defects, at the same time, the stronger assembly of SO42- than the NO3 - and C1 - was revealed. |
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| Keywords: | hexagonal mesoporous silica nano-material synthesis Characterization assembly |
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