| 二甲基氨荒酸铜配合物的合成及电化学性能研究 |
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| 引用本文： | 秦景灏,郭应臣,杨超,李亚丽,刘营营,兰亚萍.二甲基氨荒酸铜配合物的合成及电化学性能研究[J].南阳师范学院学报,2014(9):14-17. |
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| 作者姓名： | 秦景灏 郭应臣 杨超 李亚丽 刘营营 兰亚萍 |
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| 作者单位： | 南阳师范学院化学与制药工程学院,河南南阳,473061 |
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| 基金项目： | 南阳师范学院校级STP项目 |
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| 摘 要： | 以二甲胺、二硫化碳为原料合成了二甲基二硫代氨基甲酸钠,用该配体和二氯化铜合成了二甲基二硫代氨基甲酸铜.利用元素分析、红外光谱(IR)、核磁(NMR)及紫外光谱(UV)对二甲基二硫代氨基甲酸铜的结构进行了表征,并初步探讨配体的合成工艺条件.电化学性质研究表明:配合物在二氯甲烷溶液中表现出较好的可逆氧化—还原过程.
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| 关 键 词： | 二甲基二硫代氨基甲酸钠 铜(Ⅱ)配合物 合成 电化学性能 |
Synthesis and electrochemical properties of dimethyldithiocarbamate copper(II) complex |
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| QIN Jing-hao,GUO Ying-chen,YANG Chao,LI Ya-li,LIU Ying-ying,LAN Ya-ping.Synthesis and electrochemical properties of dimethyldithiocarbamate copper(II) complex[J].Journal of Nanyang Teachers College,2014(9):14-17. |
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| Authors: | QIN Jing-hao GUO Ying-chen YANG Chao LI Ya-li LIU Ying-ying LAN Ya-ping |
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| Institution: | (School of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, China) |
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| Abstract: | A method for the synthesis of the dimethyldithiocarbamate copper（Ⅱ） complex has been developed, using sodium dimethylcarbamodithioate as a ligand. The ligand could be easily obtained by the reaction of dimethylamine with carbon disulfide. The molecular structure of the copper（Ⅱ） complex was characterized by Elemental Analysis （EA） , IR, NMR, UV and the process condition for synthesizing the ligand was investigated. The studies of electrochemical properties revealed that the copper（Ⅱ） complex showed good redox process in anhydrous dichloromethane. |
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| Keywords: | sodium dimethylcarbamodithioate copper(II) complex synthesis electrochemical property |
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