| 金属-有机框架MOF-5的制备与表征 |
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| 引用本文： | 徐娜,李菁,冯占恒,邱晓航,程鹏,吴世华.金属-有机框架MOF-5的制备与表征[J].实验技术与管理,2012,29(1):49-50,55. |
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| 作者姓名： | 徐娜 李菁 冯占恒 邱晓航 程鹏 吴世华 |
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| 作者单位： | 南开大学化学学院,天津,300071 |
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| 基金项目： | 国家基础科学人才培养基金，南开大学2010精品课程建设项目 |
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| 摘 要： | 金属-有机框架是当今国际上无机化学领域的研究热点之一.设计了一个无机化学实验,即金属-有机框架MOF-5的制备及其结构表征.该实验将过渡金属盐的制备、金属-有机框架的合成和现代仪器分析技术相结合,由X射线粉末衍射对比单晶模拟谱来确定产物的结构及相纯度,并就MOF-5对N2的吸附性能进行了研究.
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| 关 键 词： | 金属-有机框架 锌 对苯二甲酸 X射线粉末衍射 吸附 |
Synthesis and characterization of porous metal-organic framework MOF-5 |
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| Xu Na
,
Li Jing
,
Feng Zhanheng
,
Qiu Xiaohang
,
Cheng Peng
,
Wu Shihua.Synthesis and characterization of porous metal-organic framework MOF-5[J].Experimental Technology and Management,2012,29(1):49-50,55. |
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| Authors: | Xu Na Li Jing Feng Zhanheng Qiu Xiaohang Cheng Peng Wu Shihua |
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| Institution: | (Department of Chemistry,Nankai University,Tianjin 300071,China) |
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| Abstract: | The study on porous metal-organic frameworks(MOFs) is one of the most attractive areas in the research field of inorganic chemistry.In this contribution,the synthesis and structure characterization of MOF-5 were introduced as an inorganic chemistry experiment,which combined the methods of the synthesis of transition metal salts and MOFs with the modern instrumental analysis technology.The structure and the phase purity can be confirmed by the comparison of PXRD patter of products with simulated XRD pattern for MOF-5 crystal.The N2 adsorption properties were also studied. |
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| Keywords: | metal-organic frameworks zinc 1 4-benzenedicarboxylic acid X-ray powder diffraction adsorption |
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