| The new modes of Palladium - catalyzed cross - coupling, dimerization and domino - tetracyclization of boroxines, trans - 1 - Bromo - 2 - styrylbenzene, and bromodienynes. A personal Ph. D. And Postdoctoral research review |
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| 作者姓名： | 宋治中 |
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| 作者单位： | 德国巴斯夫公司,上海,200135 |
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| 摘 要： | I].Synthesisandpalladium -catalyzedcross -couplingreac tionoftris4 - (trimethylsilyl)furan - 3-yl]boroxineandtris4 -(substituted)furan - 3-yl]boroxine .3,4 -Disubstitutedfuransareimportantbuildingblocksofhet erocycliccompounds,inacontinuationofthestudyonpossibleroutesto 3,4 -disubstitutedfuran ,Iwasinterestedinexploringtheroleofasilylgroupasapotentialdirectinggroupbecausesilylgroupsarewell-knownfortheir ( -donatingcharacter.Theirtendencytostabilizea ( -carbocationthroughtheso -called (p - (…
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| 修稿时间： | 2003年7月29日 |
The new modes of Palladium - catalyzed cross - coupling, dimerization and domino - tetracyclization of boroxines, trans - 1 - Bromo - 2 - styrylbenzene, and bromodienynes. A personal Ph. D. and Postdoctoral research review |
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| Abstract: | Ⅰ]. Synthesis and palladium- catalyzed cross- coupling reaction of tris4-(trimethylsilyl)furan- 3- yl] boroxine and tris4-(substituted) furan - 3 - yl ] boroxine . |
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| Keywords: | Cross- coupling reaction Suzuki reaction Heck re-action Dimerization Cyclization Domino reaction Palladium - cat-alyzed reaction Boroxine Oligomers |
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