| 茶碱分子印迹PDVB-SO3H/PDVB IPN的合成及热力学性能研究 |
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| 引用本文： | 黄淑芳.茶碱分子印迹PDVB-SO3H/PDVB IPN的合成及热力学性能研究[J].湖南科技学院学报,2006,27(11):191-193. |
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| 作者姓名： | 黄淑芳 |
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| 作者单位： | 湖南师范大学,化学化工学院,湖南,长沙,410081 |
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| 摘 要： | 以茶碱为摸板分子，采用顺序聚合法，合成了分子印迹的大孔磺化聚二乙烯基苯，聚二乙烯基苯互穿聚合物网络（PDVB—SO3H／PDVB IPN），测定了IPN的结构和热力学性能。结果表明，制备的分子印迹聚合物对印迹分子茶碱具有较好吸附作用，且能保持第一网的树脂粒径。通过热力学性能研究，讨论了IPN吸附水溶液中茶碱的机理。
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| 关 键 词： | 分子印迹 互穿聚合物网络 聚二乙烯基苯 茶碱 热力学 吸附 |
| 文章编号： | 1673-2219（2006）11-0191-03 |
| 收稿时间： | 2006-06-06 |
| 修稿时间： | 2006年6月6日 |
Preparation of PDVB-SO3H/PDVB IPN of Molecularly Imprinted for Theophylline and Study of Energetics Capability |
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| HUANG Shu-fang.Preparation of PDVB-SO3H/PDVB IPN of Molecularly Imprinted for Theophylline and Study of Energetics Capability[J].Journal of Hunan University of Science and Engineering,2006,27(11):191-193. |
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| Authors: | HUANG Shu-fang |
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| Abstract: | Molecularly imprinted and interpenetrating polymer network polymers of big pole polydivinylbenzene/Sulfonic polydivinylbenzene for theophylline were synthesized with order polymerization, and test the frame and energetics capability of the polymers result indicated, Molecularly inlprinted and interpenetrating polymer network polymers possessed preferably sorption,.and could keep the first retiary granule pathway of the polymers, overpassing the study of the energetic capability, discussed the mechanism of the adsorption Theophylline onto IPN resin from Aqueous Solution. |
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| Keywords: | Molecularly imprinted lnterpenetrating polymernetwork Polydivinylbenzene Theophylline Energetics Adsorption |
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