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亚甲基兰中性红聚合膜电极对多巴胺的分析测定
引用本文:何小荣,孙先辉,周锦,马利海,吴海霞.亚甲基兰中性红聚合膜电极对多巴胺的分析测定[J].兰州石化职业技术学院学报,2008,8(3):1-3.
作者姓名:何小荣  孙先辉  周锦  马利海  吴海霞
作者单位:[1]兰州石化职业技术学院石化系,甘肃兰州730060; [2]中国石油兰州石化公司炼油厂,甘肃兰州730060
基金项目:甘肃省教育厅科研项目,甘肃省教育厅科研项目
摘    要:在中性溶液中用重复电位扫描法在玻碳电极上制备了亚甲基兰混合中性红聚合膜。其聚合是在高电位引发下,氧化中性红和亚甲基兰产生自由基发生链式引发聚合时该聚合物修饰电极在pH值为8.4时对多巴胺有良好的催化氧化能力,在3×10^-6~3×10^-4mol/L范围与峰电流成线性关系。可用于多巴胺的测定。

关 键 词:聚亚甲基兰中性红  多巴胺  测定

Detection of Dopamine on the Poly(Methylene Blue and Neutralred) Film Modified Eectrode
HE Xiao-rong,SUN Xian-hui,ZHOU Jin,MA Li-hai,WU Haixia.Detection of Dopamine on the Poly(Methylene Blue and Neutralred) Film Modified Eectrode[J].Journal of Lanzhou Petrochemical Vocational College of Technology,2008,8(3):1-3.
Authors:HE Xiao-rong  SUN Xian-hui  ZHOU Jin  MA Li-hai  WU Haixia
Institution:HE Xiao- rong, SUN Xian- hui , ZHOU Jin, MA Li- hai, WU Haixia (1. Lanzhou Petroehemieal College of Vocational Technology, Lanzhou 730060, China; 2. Lanzhou Petroehemieal Company, PetroChina, Lanzhou 730060, China )
Abstract:The formation of a radical cation, by electrochemical oxidation of the methylene blue and neutral red dye in neutral aqueous solution, is controlled by diffusion towards the glassy carbon electrode surface. The modified electrode was an effective mediator for the electrocatalytic oxidation of the dopamine and the modification allowed dopamine to be determined in the range of 3×10^-6~3×10^-4mol/L in pH 8.4 tris -HCI buffer solution.
Keywords:Poly(methylene blue neutral red)  dopamine  determination
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