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5-乙酰硫苯基-10,15,20-三苯基卟啉的合成和循环伏安性质研究
引用本文:李长恭,尚静艳.5-乙酰硫苯基-10,15,20-三苯基卟啉的合成和循环伏安性质研究[J].河南职业技术师范学院学报,2011(5):58-63.
作者姓名:李长恭  尚静艳
作者单位:河南科技学院,河南新乡453003
基金项目:国家自然科学基金(21072046); 河南科技学院高学历人才资助项目(08009)
摘    要:合成了5-乙酰硫苯基-10,15,20-三苯基卟啉(AcS-TPP),用熔点、红外光谱、核磁共振表征了相关化合物的结构.用电化学循环伏安方法研究了5-乙酰硫苯基-10,15,20-三苯基卟啉及相关化合物5-甲硫基苯基-10,15,20-三苯基卟啉(CH3S-TPP)和5,10,15,20-四苯基卟啉(TPP)的循环伏安性质.

关 键 词:卟啉  合成  结构表征  循环伏安

Synthesis and cyclic voltammetry property of 5-Acetylthiophenyl-10,15,20-triphenylporphyrin
Li Changgong,Shang Jingyan.Synthesis and cyclic voltammetry property of 5-Acetylthiophenyl-10,15,20-triphenylporphyrin[J].Journal of Henan Vocation-Technical Teachers College,2011(5):58-63.
Authors:Li Changgong  Shang Jingyan
Institution:(Henan Institute of Science and Technology,Xinxiang 453003,China)
Abstract:The acetylthiophenylporphyrin was synthesized from p-methylthiobenzaldehyde,benzaldehyde and pyrrole.The structures of all the products were characterized by melting point,IR,and 1H-NMR.The cyclic voltammetry properties of acetylthiophenylporphyrin and related porphyrin were investigated by electrochemistry method.
Keywords:porphyrin  synthesis  structure characterization  cyclic voltammetry
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