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原子吸收法间接测定水中的硫酸根
引用本文:侯占忠. 原子吸收法间接测定水中的硫酸根[J]. 河北北方学院学报(社会科学版), 2003, 19(6): 65-71
作者姓名:侯占忠
作者单位:河北北方学院化学系,张家口,075000
摘    要:根据SO42-与Ba2+反应生成BaSO4沉淀,用原子吸收法测定溶液中剩余的Ba2+,进而间接求出水中的SO42-含量.在5ml水样中加入1.75mlBa2+(1mg/ml),经一定时间的陈化后,用原子吸收法测定水样中的Ba2+,利用先作好的标准曲线,得到水样中的SO42-的量.用于不同类型的水样分析,对于河水中的硫酸根的测定标准偏差为0.0012,相对标准偏差为2.87%.

关 键 词:原子吸收法    钡离子(Ba2+)  硫酸根(SO42-)
文章编号:1008-2727(2003)03-065-07
修稿时间:2003-06-10

The Indirect Determination of the Acid Radical in Water with Atomic Absorption
Hou Zhanzhong. The Indirect Determination of the Acid Radical in Water with Atomic Absorption[J]. Journal of Hebei North University, 2003, 19(6): 65-71
Authors:Hou Zhanzhong
Abstract:This paper studies the application of the method of Atomic Absorption to determine the content of SO42- in water indirectly. In accordance with the reaction between SO42- and Ba2+ with the sediment of BaSO4, this paper expounds the application of Atomic Absorption in determining the remaining Ba2+ in the solution and the indirect calculation of the content of SO42- in water. The procedures are as follows: put Ba2+ 1. 75ml of (1mg/ml) in the water sample; after a certain time, determine the content of Ba2+ in the water sample with the Method of Atomic Absorption; then by the means of a prepared standard curve the content of SO42- in water can be obtained. This method can also be applied in the analysis of various types of water sample. The standard deviation in the determination of SO42- in river water is 0.0012 and comparative standard deviation is 2.87%.
Keywords:Method of Atomic Absorption  water  SO42-  Ba2+  
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