Concise Strategies to Enhance the High-Rate Performance of Li3VO4 Anodes: Cl Doping,Carbon Coating,and Spherical Architecture Design |
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作者姓名: | Zongping Zhang Jie Xu Dongmei Zhang Huijuan Ma Tao Li Ting Xiao Cunyuan Pei Shibing Ni |
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作者单位: | 1. College of Materials and Chemical Engineering,Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials,China Three Gorges University;3. Analysis and Testing Center,China Three Gorges University;4. College of Electrical Engineering and New Energy,China Three Gorges University |
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基金项目: | supported by the National Natural Science Foundation of China (No. 52101262);;the 111 project (D20015); |
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摘 要: | The safe operating voltage and low volume variation of Li3VO4(LVO) make it an ideal anode material for lithium(Li)-ion batteries.However,the insufficient understanding of the inner storage mechanism hinders the design of LVO-based electrodes.Herein,we investigate,for the first time,the Li-ion storage activity in LVO via Cl doping.Moreover,N-doped C coating was simultaneously achieved in the Cl doping process,resulting in synergistically improved reaction kinetics.As a resul...
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