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Metal-organic frameworks enable broad strategies for lithium-sulfur batteries
Authors:Cheng Zhou  Zhaohuai Li  Xu Xu  Liqiang Mai
Affiliation:State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China;International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China;Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Foshan 528200, China
Abstract:The lithium-sulfur (Li-S) battery is considered to be a potential next-generation power battery system, however, it is urgent that suitable materials are found in order to solve a series of challenges, such as the shuttle effect and lithium dendrite growth. As a multifunctional porous material, metal-organic frameworks (MOFs) can be used in different parts of Li-S batteries. In recent years, the application of MOFs in Li-S batteries has been developed rapidly. This review summarizes the milestone works and recent advances of MOFs in various aspects of Li-S batteries, including cathode, separator and electrolyte. The factors affecting the performance of MOFs and the working mechanisms of MOFs in these different parts are also discussed in detail. Finally, the opportunities and challenges for the application of MOFs in Li-S batteries are proposed. We also put forward feasible solutions to related problems. This review will provide better guidance for the rational design of novel MOF-based materials for Li-S batteries.
Keywords:metal-organic frameworks   lithium-sulfur batteries   cathode   separator   electrolyte
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