|
|||||
|
|
| 屏蔽-钻穿常数与碳正离子的稳定性 | |
| 引用本文： | 曹晨忠.屏蔽-钻穿常数与碳正离子的稳定性[J].湘潭师范学院学报(社会科学版),1993(3). |
| 作者姓名： | 曹晨忠 |
| 摘 要： | 用碳自由基的电离能计算其屏蔽一钻穿常数S_(R(C))~′,可定量碳正离子的稳定性。并且S_(R(C))~′与键离解能DH°(R~+/X~-),分子(RX)的电离能Ip_((RX))及醇、胺的质子亲合能PA有良好的线性关系。 |
| 关 键 词： | 屏蔽—钻穿常数 碳正离子 键离解能 质子亲分能 |
The Penetrating-Shielding Constant and Its Stability for Carbocation |
|
| Cao chehzhong.The Penetrating-Shielding Constant and Its Stability for Carbocation[J].Journal of Xiangtan Normal University(Social Science Edition),1993(3). | |
| Authors: | Cao chehzhong |
| Institution: | Cao chehzhong |
| Abstract: | |
| Keywords: | Penetrating-shielding constant Carboeation Bond dissociation enthalpy Proton affinity enegy |
| 本文献已被 CNKI 等数据库收录！ | |