| Unraveling the electrophilic oxygen-mediated mechanism for alcohol electrooxidation on NiOOA |
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| 作者姓名： | Wei Chen Jianqiao Shi Chao Xie Wang Zhou Leitao Xu Yingying Li Yandong Wu Binbin Wu Yu-Cheng Huang Bo Zhou Ming Yang Jilei Liu Chung-Li Dong Tehua Wang Yuqin Zou Shuangyin Wang |
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| 作者单位： | 1. State Key Laboratory of Chemo/Bio-Sensing and Chemometrics,College of Chemistry and Chemical Engineering,Advanced Catalytic Engineering Research Center of the Ministry of Education,Hunan University;2. College of Chemistry and Chemical Engineering,Hunan Normal University;3. College of Materials Science and Engineering,Hunan University;4. Research Center for X-ray Science&Department of Physics,Tamkang University;5. Shenzhen Institute of Hunan University |
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| 基金项目： | supported by the National Key R&D Program of China (2020YFA0710000)；;the National Natural Science Foundation of China (22122901,21902047,21825201 and U19A2017)；;the Provincial Natural Science Foundation of Hunan (2020JJ5045,2021JJ20024 and2021RC3054)；;the Shenzhen Science and Technology Program (JCYJ20210324140610028)； |
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| 摘 要： | Aqueous organic electrosynthesis such as nucleophile oxidation reaction(NOR) is an economical and green approach.However,its development has been hindered by the inadequate understanding of the synergy between the electrochemical and non-electrochemical steps.In this study,we unravel the NOR me chanism for the primary alcohol/vicinal diol electro oxidation on NiO.Thereinto,the ele ctrochemical step is the generation of Ni3+-(OH)ads,and the spontaneous reaction between Ni
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