| 硫酸铜催化合成癸二酸二丁酯的研究 |
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| 引用本文： | 邓斌,黄海英,刘国军.硫酸铜催化合成癸二酸二丁酯的研究[J].宜春学院学报,2003,25(6):4-5,7. |
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| 作者姓名： | 邓斌 黄海英 刘国军 |
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| 作者单位： | 1. 湘南学院,化学系,湖南,郴州,423000
2. 中山大学化学化工学院,广东,广州,510275 |
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| 基金项目： | 湖南省教育厅科技处资助项目(0 1C0 1 0)，湘南学院青年骨干教师培养对象基金 |
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| 摘 要： | 利用硫酸铜作为酯化反应催化剂合成了癸二酸二丁酯，其最佳反应条件为：催化剂用量3．0g/0．05mol癸二酸，醇酸摩尔比为4，反应时间3．0h，带水剂12ml，癸二酸的酯化率可达97．23％，该催化剂催化效果好，使用量少，酯化率高，可重复使用，无环境污染，价廉易得，是一种极有应用价值的催化剂。
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| 关 键 词： | 癸二酸二丁酯 硫酸铜 催化 合成 酯化反应 |
| 文章编号： | 1671-380X(2003)06-0004-03 |
Catalytic Synthesis of Dibutyl Sebacate with Cupric Sulphfate |
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| DENG Bin ,HUANG Hai-ying ,LIU Guo-jun.Catalytic Synthesis of Dibutyl Sebacate with Cupric Sulphfate[J].Journal of Yichun University,2003,25(6):4-5,7. |
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| Authors: | DENG Bin HUANG Hai-ying LIU Guo-jun |
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| Institution: | DENG Bin 1,HUANG Hai-ying 1,LIU Guo-jun 2 |
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| Abstract: | Use of cupric sulphfate as catalyst on the esterification of dibutyl sebacate was studied The optimized conditions are as following:the weight of catalyst is 3 0g/0 05mol sebacic acid,the mole ratio of alchol to acid is 4,the reaction tim is 3 0h and 12ml benzene as water carrier The esterification yield for sebacic acid is about 97 23% Experimental results showed that cupric sulfate is a highly active catalyst for this reaction Less catalyst is required with little waste dischargement It is an inexpensive and very practical method |
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| Keywords: | dibutyl sebacate cuprisulphfate cata lysis synthesis |
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