| 无溶剂条件下锌粉促进Aza-Michael加成反应 |
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| 引用本文： | 张霞忠,周娇,周文俊.无溶剂条件下锌粉促进Aza-Michael加成反应[J].内江师范学院学报,2012,27(6):33-36. |
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| 作者姓名： | 张霞忠 周娇 周文俊 |
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| 作者单位： | 1. 内江师范学院化学化工学院／／果蔬类废弃物资源化四川省高等学校重点实验室,四川内江,641100
2. 绵阳师范学院化学化工学院,四川绵阳,621000 |
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| 摘 要： | 研究了Zn粉促进的aza-Michael加成反应，通过利用胺类化合物与α，β-不饱和酯类化合物的共轭加成，成功实现了无溶剂条件下β-氨基酯的环境友好合成．反应避免了有机溶剂的使用，实现了反应物、催化剂和产品的绿色化，尽可能的实现了零排放．
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| 关 键 词： | aza—Michael加成 β-氨基酯 锌粉 无溶剂 |
Aza-Michael Addition Reaction Boosted by Zinc Powder Under Solvent-free Condition |
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| ZHANG Xia-Zhong,ZHOU Jiao,ZHOU Wen-jun.Aza-Michael Addition Reaction Boosted by Zinc Powder Under Solvent-free Condition[J].Journal of Neijiang Teachers College,2012,27(6):33-36. |
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| Authors: | ZHANG Xia-Zhong ZHOU Jiao ZHOU Wen-jun |
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| Institution: | 1.College of Chemistry and Chemical Engineering//Key Laboratory of Fruit Waste Treatment and Resource Recycling of the Sichuan Provincial Higher Learning Institutes,Neijiang Normal University, Neijiang,Sichuan 641100,China;2.College of Chemistry and Chemical Engineering,Mianyang Normal University,Mianyang,Sichuan 621000,China) |
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| Abstract: | A rapid and efficient aza-Michael addition of aliphatic amines wit electron-deficient alkenes promoted by zinc powder under solvent-free conditions was reported,and the corresponidng β amino ester compound was obtained in good to excellent yields.The reaction avoided the use of lrganic solvents,which renders the methodology highly valuable from both environment and economic points of view. |
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| Keywords: | aza-Michael addition β-amino ester zinc powder solvent-free |
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