| Zn/AlCl_3对高烯丙基醇无溶剂合成的影响 |
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| 引用本文： | 严文君,甘贤雪,王丽,李娜.Zn/AlCl_3对高烯丙基醇无溶剂合成的影响[J].内江师范学院学报,2010,25(10):46-48. |
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| 作者姓名： | 严文君 甘贤雪 王丽 李娜 |
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| 作者单位： | 宜宾学院化学化工学院,四川宜宾644007 |
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| 摘 要： | 在室温无溶剂条件下,Zn/AlCl3能够促进芳香醛和烯丙基溴发生烯丙基化反应合成高烯丙基醇,该方法具有环境友好、操作简便、产率高等特点.产物的结构经IR和1H NMR确证.
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| 关 键 词： | Zn/AlCl3 高烯丙基醇 醛 无溶剂 |
The Solvent-free Synthesis of Homoallyl Alcohols by Promotion of Zn/AlCl3 |
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| YAN Wen-jun,GAN Xian-xue,WANG Li,LI Na.The Solvent-free Synthesis of Homoallyl Alcohols by Promotion of Zn/AlCl3[J].Journal of Neijiang Teachers College,2010,25(10):46-48. |
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| Authors: | YAN Wen-jun GAN Xian-xue WANG Li LI Na |
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| Institution: | (College of Chemistry and Chemical Engineering,Yibin University,Yibin,Sichuan 644007,China) |
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| Abstract: | Under solvent-free conditions,it was found that Zn/AlCl3 could efficiently mediate the carbonyl allylation reaction of aldehyde and allyl bromide to give the corresponding homoallylic alcohols at room temperature.The merits of this protocol are environmentally benign,and characterized by simple operation,convenient work-up and good yields.The structures of the products were confirmed by IR and 1H NMR. |
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| Keywords: | Zn/AlCl3 homoallyl alcohol aldehyde solvent-free |
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