| 苦味酸锰、钴、镍、铜、锌、镉与4′─硝基苯并─15─冠─5配合物的合成与表征 |
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| 引用本文： | 申义阳,吉保明,陈花婷,张长水,韩相明.苦味酸锰、钴、镍、铜、锌、镉与4′─硝基苯并─15─冠─5配合物的合成与表征[J].洛阳师范学院学报,1997(5). |
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| 作者姓名： | 申义阳 吉保明 陈花婷 张长水 韩相明 |
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| 作者单位： | 洛阳师专化学系!洛阳471022(申义阳，吉保明，陈花婷)，洛阳农业高等专科学校!洛阳471003(张长水)，平原大学化工系!新乡453003(韩相明) |
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| 摘 要： | 在乙腈─乙醇─水（2：2：1，V／V／V）的混合溶剂中制备了六种金属（锰、钴、镍、铜、锌、镉）苦味酸盐与4′─硝基苯并─15─冠─5的固态配合物，其组成为M（pic）2·2L·XH2（M＝Mn、CU，x＝2；M＝Co，Ni，Zn，Cd，x＝4；pic＝苦味酸根；L＝4′─NO2B15CS），并通过元素分析、红外光谱、紫外光谱和摩尔电导对该系列配合物进行了表征。
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| 关 键 词： | 配合物 4′─硝基苯并─15─冠─5 苦味酸盐 |
Syntheses and Characterization of Nitro- 4' -Benzo-15-Crown-5 and its M (M=Mn~(2 ), Co~(2 ), Ni~(2 ), Cu~(2 ), Zn~(2 ),Cd~(2 ))picrate Complexes |
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| Shen Yiyang,Ji Baoming ,Chen Huating.Syntheses and Characterization of Nitro- 4' -Benzo-15-Crown-5 and its M (M=Mn~(2 ), Co~(2 ), Ni~(2 ), Cu~(2 ), Zn~(2 ),Cd~(2 ))picrate Complexes[J].Journal of Luoyang Teachers College,1997(5). |
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| Authors: | Shen Yiyang Ji Baoming Chen Huating |
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| Abstract: | Six kinds of Nitro - 4' - Benzo - 15 - Crown - 5 (L) complexes having the stoichometric formula M(pic)2· 2L· xH2O (M=Mn, Cu, x=2; M =Co, Ni, Zn, Cd,x=4; pic=picrate anion) have been prepared in a 2 : 2: 1 (V/V/V) mixed solvent of MeCN, EtOH and H2O, and Characterized by EA、IR、UV and Molar conductance. It was found that the ligand with the hydrated transition metal picrate by hydrogen bonding of coordinating water molecules and all the complexes prepared are nonelectrolytes in acetone. |
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| Keywords: | complex nitro-4'-Benzo-15-Crown-5 picrate |
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