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| 有机共轭体系的设计与组装 | |
| 引用本文： | 李勇军,李玉良,朱道本.有机共轭体系的设计与组装[J].中国科学院研究生院学报,2008,25(1):136-143. |
| 作者姓名： | 李勇军 李玉良 朱道本 |
| 作者单位： | 1. 中国科学院化学研究所有机固体院重点实验室,北京,100080;中国科学院研究生院,北京,100049 2. 中国科学院化学研究所有机固体院重点实验室,北京,100080 |
| 基金项目： | the Project of the National Nature Science Foundation of China , 国家重点基础研究发展计划(973计划) , National Center for Nanoscience and Technology, China |
| 摘 要： | 本论文围绕有机共扼大π体系这一主题，利用共价键、配位键及弱相互作用如氢键、π-π堆积、亲水-疏水作用设计了一系列自组装超分子结构，在具有光电转换性能的给受体系、配位聚合物、光驱动的分子机器、空心胶囊等几个方面开展了一系列研究工作。 |
| 关 键 词： | 共扼体系 自组装 分子机器 光环合反应· 给受体系 |
| 文章编号： | 1002-1175(2008)01-0136-08 |
| 修稿时间： | 2006年12月18 |
Synthesis and self-assemble of organic π-conjugated systems |
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| LI Yong-Jun,LI Yu-Liang,ZHU Dao-Ben.Synthesis and self-assemble of organic π-conjugated systems[J].Journal of the Graduate School of the Chinese Academy of Sciences,2008,25(1):136-143. | |
| Authors: | LI Yong-Jun LI Yu-Liang ZHU Dao-Ben |
| Institution: | a. Key Laboratory of Organic Solids, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China, b. Graduate School, Chinese Academy of Sciences, Beijing 100049, P. R. China |
| Abstract: | Organic π-conjugated systems such as porphyrin, perylene bisimide, pyrene, fullerene,ferrocene have been synthesized and their self-assembly based on specific molecular interaction have been studied. The self-assembly into more complicated systems such as molecular machine and light-to-current converter have also been studied. |
| Keywords: | π-conjugated systems self-assembly molecular machine photocyclization donor-accepter |
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