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Electrochemical detection of hydrogen peroxide at a waxed graphite electrode modified with platinum-decorated carbon nanotubes
Authors:Qiao-cui Shi  Wen-fang Zeng  Yu-nu Zhu
Institution:1. Experience Center, Zhejiang Police College, Hangzhou 310053, P. R. China
2. Department of Chemistry, Zhejiang University, Hangzhou 310028, P. R. China
Abstract:Platinum-decorated carbon nanotubes (CNT-Pt) were produced by the chemical reduction method. A novel modified electrode was fabricated by intercalated CNT-Pt in the surface of waxed graphite, which provided excellent electro-catalytic activity and selectivity for both oxidation and reduction of hydrogen peroxide. The current response of the modified electrode for hydrogen peroxide was very rapid and the detection limits in amperometry are 2.5×10-6 mol/L at reduction potential and 4.8×10-6 mol/L at oxidation potential. It was desmonstrated that the electrode with high electro-activity was a suitable basic electrode for preparing enzyme electrode.
Keywords:platinum-decorated carbon nanotubes (CNT-Pt)  hydrogen peroxide  electroanalysis
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