Reductive cyclodimerization of arylmethylidenemalononitriles promoted by samarium and catalytic amount of iodine: facile synthesis of cyclopentene derivatives期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Reductive cyclodimerization of arylmethylidenemalononitriles promoted by samarium and catalytic amount of iodine: facile synthesis of cyclopentene derivatives

Authors:	Chen?Jue author-information" > author-information__contact u-icon-before" > mailto:chenjue@hkem.com" title=" chenjue@hkem.com" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,Zhang?Yong-min

Affiliation:	(1) Ningbo Institute of Technology, Zhejiang University, 315104 Ningbo, China;(2) Department of Chemistry, Zhejiang University, 310028 Hangzhou, China;(3) State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of science, 200032 Shanghai, China

Abstract:	Samarium and a catalytic amount of iodine were used to obtain functionalized cyclopentenes by reductive dimerization followed by intramolecular cyclization of 1,1-dicyanoalkenes under mild conditions. Preject (No. 20072033) supported by the National Natural Science Foundation of China, and Zhejiang Provincial Natural Science Foundation of China

Keywords:	Metallic samarium Catalyzed by iodine 1,1-dicyanoalkenes Reductive cyclodimerization Cyclopentene derivatives
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