| Science Letters:A novel reduction of diketones with i-RMgBr catalyzed by Cp_2TiCl_2 and deoxygenation of sulfoxides by Cp_2TiCl_2/Al system |
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| 引用本文： | 张永敏,林茂钦,俞永平. Science Letters:A novel reduction of diketones with i-RMgBr catalyzed by Cp_2TiCl_2 and deoxygenation of sulfoxides by Cp_2TiCl_2/Al system[J]. Journal of Zhejiang University. Science. B, 2004, 0(10) |
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| 作者姓名： | 张永敏 林茂钦 俞永平 |
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| 作者单位： | Department of Chemistry，Zhejiang University，Hangzhou 310028，China State Key Laboratory of Organometallic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China，Department of Chemistry，Zhejiang University，Hangzhou 310028，China，Department of Chemistry，Zhejiang University，Hangzhou 310028，China |
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| 基金项目： | Project (No. 20072033) supported by the National Natural Science Foundation of China and the Specialized Research Fund for the Doctoral Program of Higher Education Ministry, China |
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| 摘 要： | α-diketones and β-diketones react with Grignard reagents in the presence of a catalytic amount of Cp2TiCl2 to yield α-ketols and corresponding ketones respectively. Sulfoxides can be deoxygenated by Cp2TiCl2/Al system. The possible mechanisms are also discussed.
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| 关 键 词： | Grignard reagent Cp2TiCl2-catalyzed α-diketone β-diketone Reduction |
Science Letters:A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system |
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| ZHANG Yong-min,LIN Mao-qin,YU Yong-ping. Science Letters:A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system[J]. Journal of Zhejiang University. Science. B, 2004, 0(10) |
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| Authors: | ZHANG Yong-min LIN Mao-qin YU Yong-ping |
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