根据螺旋理论推断脂肪族化合物的绝对构型 |
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作者姓名: | 尹玉英 刘春蕴 |
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作者单位: | 北京石油化工学院化工系, 北京 102600 |
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基金项目: | 国家自然科学基金资助项目(29542006) |
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摘 要: | 脂肪族光学活性化合物,特别是链状化合物,可根据笔者提出的螺旋理论,对几个较稳定的构象进行计算,由计算结果和构象分析确定其旋光方向,再与测定的旋光方向相对照,同样可以推断出其绝对构型
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关 键 词: | 脂肪族化合物 光学活性 螺旋理论 绝对构型推断 |
收稿时间: | 2000-08-20 |
The Predictoin of the Absolute Configuration of Aliphatic Compound |
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Authors: | Yin Yuying Liu Chunyun |
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Institution: | Department of Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102600 |
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Abstract: | On the basis of the helix theory proposed by the authors, some stable conformations can be calculated especially chain compounds. According to the calculation and conformation analysis their rotatory direction will be ditermined, and the absolute configuration can be deduced. |
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Keywords: | aliphatic compound optical activity the helix theory predictoin of the configuration |
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