The binding media of the polychromy of Qin Shihuang's Terracotta Army

The “Terracotta Army” is a worldwide known archaeological finding in China. It is a part of the burial complex of the emperor Qin Shihuangdi (259–210 BC), which is still under excavation and study. The fact that the sculptures, chariots and weapons of the First Chinese Emperor's Terracotta Army were originally all painted in bright colours is still not widely known. The chemical characterisation of the paint medium was performed through an analytical procedure based on GC-MS. The proteinaceous binder was identified for the first time through a desalting procedure used in proteomics. The identification of egg as a paint binder is extremely interesting in terms of the historical significance of the work of art itself and important in terms of the method of conservation. Moreover it represents one of the first steps towards an understanding of the painting technique used on ancient sculptures in China, of which – despite their fame – nothing is yet known.     

纤维与沥青胶浆粘附性新型测试仪器的应用

为推广应用自制的新型沥青胶浆纤维拉拔试验机,使用其对沥青胶浆和玄武岩纤维之间的粘附性进行了研究,并采用最大粘结强度来表征二者的粘附性。采用两种不同产地的玄武岩纤维,在4种粉胶比(0.8、1.0、1.2、1.4)、3种纤维埋置长度(12、20、30 mm)下进行试验,并采用灰色关联分析等方法对试验数据进行了分析。结果表明:最大粘结强度与粉胶比成正相关关系;纤维与沥青胶浆的粘附性与纤维的埋置长度、聚集状态关系不大;在纤维埋置长度20 mm下试验数据最为稳定,建议作为试验测试条件。对试验结果进行拟合和推算可以在试验范围内较好地量化表征玄武岩纤维与沥青胶浆的粘附性指标,经过研究提出了几种常用沥青混合料规范计算粉胶比对应的拉拔试验粘结强度要求,可以作为市场上玄武岩纤维质量检验的参考,为玄武岩纤维与沥青胶浆粘附性评价及不同生产厂家玄武岩纤维的质量检验奠定了一定的基础。     

废腈纶在型砂黏合剂中的应用研究

用废腈纶经催化水解制得了一种新型铸造黏合剂 ,探讨了影响样砂抗拉强度的各种因素 ,结果表明 ,该黏合剂具有砂强度高、溃散性好 ,发气量少 ,无污染等优良特点     

复合淀粉粘合剂的研制

介绍了两种新的淀粉粘合剂的制备方法，该产品制法简单、稳定性好、粘度高、渗透性强、成膜性较好，有较好的使用前景。     

浇注式沥青混合料高温性能研究

车辙是正交异性钢桥面沥青混凝土铺装主要病害之一 .采用汉堡轮辙试验机 ,提出了适宜于德国、考察浇注式沥青混合料高温性能的试验条件 ,测试和比较了不同浇注式沥青混合料的高温性能 .聚合物改性沥青混合料具有较高的抗车辙能力 .滞留时间和拌和频率对浇注式沥青混合料的性能有明显的影响     

复合胶凝材料配伍技术研究

武广客专设计时速为350km／h,设计使用寿命为100年,对混凝土的耐久性等提出很高的要求,按普通配合比设计规范设计采用单一的胶凝材料配制混凝土已不能满足高性能混凝土的质量要求,复合混凝土胶凝材料,将胶凝材料中的两种、三种、或四种进行复配,通过试验确定其最佳复配比例,然后将其掺入混凝土中改善混凝土的性能,对各种胶凝材料的配制技术的研究,减少了高性能混凝土配合比的设计时对选材的困惑。     

Chemical characterization and AMS radiocarbon dating of the binder of a prehistoric rock pictograph at Tadrart Acacus, southern west Libya

The analysis of the amino acid (AA) content in fragments derived from a prehistoric rock pictograph (Lancusi rock shelter) at Tadrart Acacus, southern west Libya, revealed the presence of material containing peptides differing in solubility in hot acidic or alkaline solutions, as well as in AA composition and racemization. Water-soluble components were constituted of low molecular weight peptides with high racemization of aspartic acid and alanine, whereas the water insoluble material consisted of species of a more complex AA composition and a different degree of racemization. The proteinaceous materials were assumed to originate from matter that had undergone over time different diagenetic processes. The water insoluble peptide-containing material was separated from the rock substrate by acid hydrolysis, dried and the resulting residue submitted to radiocarbon analysis. Accelerator mass spectrometry (AMS) yielded an approximate age of 6145 ± 70 years B.P. (before present), which is consistent with archaeological inference and the climatic reconstruction of central Sahara. To our knowledge the present work represents the first attempt of direct radiocarbon dating of rock art in the Sahara desert.     

基于路面使用性能和全寿命周期费用的永久性路面结构对比分析(英文)

研究了江苏省沿江高速公路永久性路面试验段的路面使用性能和经济适用性.对试验段路面性能进行连续监测,对比了通车以后8年内含有富油抗疲劳层(RBL)的永久性路面、不含富油抗疲劳层的永久性路面与普通半刚性基层沥青路面的弯沉、裂缝和车辙状况及发展规律,并通过全寿命周期费用分析法(LCCA)对各路段进行经济评价.通过性能对比和LCCA分析发现:含富油抗疲劳层的沥青结构具有良好的抗裂缝性能,但是抗永久性变形能力不足;传统的半刚性基层沥青路面因在服务寿命内需要更频繁的养护而经济性不足.研究结果表明:不含富油抗疲劳层的永久性路面结构是本地较为适用的一种永久性路面结构.     

MGB probe assay for rapid detection of mtDNA11778 mutation in the Chinese LHON patients by real-time PCR

Objective:Leber's hereditary optic neuropathY (LHON)is a maternally inherited degeneration of the optic nerve caused by point mutations of mitochondrial DNA(mtDNA).Many unsolved questions regarding the penetrance and pathophysiological mechanism of LHON demand efficient and reliable mutation testing.This study aims to develop a minor groove binder(MGB) probe assay for rapid detection of mtDNA11778 mutation and heteroplasmy in Chinese LHON patients by real-time polymerase chain reaction(PCR).Methods:Forty-eight patients suspected of having LHON and their maternal relatives underwent a molecular genetic evaluation,with 20 normal individuals as a control group at the same time.A real-time PCR involving two MGB probes was used to detect the mtDNA 11778 mutation and heteroplasmy.A linear standard curve was obtained by pUCmLHONG and pUCmLHONA clones.Results:All 48 LHON patients and their matemal relatives were positive for mtDNA 11778 mutation in our assay,27 heteroplasmic and 21 homoplasmic.Eighteen cases did not show an occurrence of the disease,while 9 developed the disease among the 27 heteroplasmic mutation cases.Eleven did not show an occurrence of the disease,while 10 cases developed the disease among 21 homoplasmic mutation cases.There was a significant difierence in the incidence between the heteroplasmic and the homoplasmic mutation types.The time needed for running a real-time PCR assay was only 80 min.Conclusion:This real-time PCR assay is a rapid,reliable method for mtDNA mutation detection as well as heteroplasmy quantification.Detecting this ratio is very important for predicting phenotypic expression of unaffected carriers.     

MIM方法制备高硬度不锈钢剪刀的工艺研究

用金属粉末注射成型的方法制备高硬度合金剪刀,其喂料使用440型不锈钢粉末和PEG/PMMA复合粘结剂制成。前人对该问题的研究主要集中在440型不锈钢粉末的PIM成型方法上,而本文结果表明:通过精确控制粉末的烧结条件和热处理工艺,就可以获得硬度高、粉末分布均匀、碳化物球化良好的制品。