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通过溶胶凝胶法,分别采用柠檬酸、酒石酸、葡萄糖、蔗糖、EDTA作为络合剂制备LaSrFeCoO6催化剂,以催化甲烷燃烧为目标反应,考察催化剂的活性。通过比表面积测定(BET)、X射线衍射分析(XRD)、氢还原(H2-TPR)、扫描电镜(SEM)及热分析(TG-DSC)等技术对催化剂进行性能表征。考察不同络合剂对LaSrFeCO6催化剂结构和性能影响。通过实验结果可以得到:经过800℃高温焙烧后,催化剂具有完整的钙钛矿晶型。不同络合剂对催化剂的结构和性能有较大影响;柠檬酸作为络合剂时,所制备LaSrFeCO6催化剂具有较好的催化活性,T10%(起燃温度)为425℃,T90%(完全转化温度)为600℃。 相似文献
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采用溶胶-凝胶法制备了SrTiO3及其镁掺杂的钙钛矿型复合氧化物超细微粒催化剂,应用TEM、XRD等手段,研究所得超细微粒催化剂的粒子大小、组成结构与OCM反应催化性能。结果表明:高温、粒子细化、B位掺杂对OCM反应CH4的转化率、C2选择性都有提高。750℃时,SrTi0.9Me0.1O3对OCM反应的甲烷转化率为28.9%,C2选择性为60.0%。 相似文献
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利用酸催化的快速溶胶-凝胶法(sol-gel)制备了一系列不同La3+掺杂量(x=0.01%~3%)的TiO2复合光催化剂;在太阳光条件下,以亚甲基蓝溶液的光催化降解为模型反应,研究了染料的光催化降解动力学行为,考察了催化剂投加量和La3+掺杂量对复合光催化剂活性的影响.结果表明,亚甲基蓝的光催化降解反应遵循Langmuir-Hinshelwood动力学模型,表观反应速率常数随着反应体系中催化剂用量和La3+掺杂量的不同而不同,均存在一个最佳值.在本实验条件下,当催化剂投加量为1.5g/L,La3+掺杂量为0.5%时,测得表观反应速率常数为2.1.×10-2mg(L·min)-1,反应120min后亚甲基蓝的降解率可达91.55%. 相似文献
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通过固相反应法制备了La离子掺杂的BaZr0.15 Ti0.35 O3(BZT)陶瓷.研究了La离子掺杂对BZT陶瓷的晶体结构、微观形貌和介电性能的影响.X射线衍射表明,所制备的BZT陶瓷均为钙钛矿赝立方相,La离子添加后衍射峰向高角度偏移;拉曼光谱测试表明,[A1(TO3)]拉曼峰加强,且没有杂相生成,La离子掺杂后... 相似文献
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邓存 《宁德师专学报(自然科学版)》2000,(1)
应用XRD、TPR和催化活性评价手段 ,考察了助剂对CH4 与CO2 重整制合成气的负载型Ni催化剂的最大分散量和其催化性能的影响 .实验结果表明 ,在反应温度为 750℃和空速为2 50 0h- 1下 ,NiO载量为 14%NiO/γ -Al2 O3催化剂具有最佳的反应性能 ,NiO在γ -Al2 O3表面上最大分散量为 0 .2 38gNiO/gγ -Al2 O3(相当于 0 .112gNiO/10 0m2 γ -Al2 O3) ,其最大分散量随MgO、La2 O3助剂的添加不同程度地增大 ;助剂能影响负载型Ni催化剂的催化性能 ,MgO、La2 O3的添加对改善Ni催化剂的重整活性和抗积炭能力有明显效果 .La2 O3助剂的突出作用表现在维持Ni为低价还原态和促进CO2 转化等方面 . 相似文献
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采用溶胶-凝胶法制备了系列La3+掺杂的纳米TiO2,用X射线衍射(XRD)、扫描电镜(SEM)、X-射线能谱仪(EDS)等测试方法对催化剂进行表征,并以甲基橙溶液为降解目标,测定其紫外光光催化活性.结果表明:La3+的掺杂能有效抑制TiO2纳米颗粒的增长,提高晶相转变温度;稀土La3+的掺杂能有效提高TiO2纳米粉体的光催化活性,最佳初始掺杂物质的量比为0.02%. 相似文献
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考察了不同Ni担栽量的Ni/α-Al2O3催化剂对甲烷部分氧化的催化性能的影响和助剂Ce对Ni基催化剂性能的调变作用.采用沉淀法以NH3·H2O、Al(NO3)3·9H2O和Ni(NO3)3·6H2O为原料合成Ni/α-Al2O3凝胶,经过高温煅烧制备纳米级催化剂Ni/α-Al2O3粉末.通过固定床反应器进行催化剂的活性评价,并对其进行XRD和TPR分析.结果表明:8%Ni(质量分数)的Ni/α-Al2O3催化剂催化活性最佳,同时添加稀土Ce有助于提高催化剂的活性、选择性和稳定性. 相似文献
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樊光银 《赤峰学院学报(自然科学版)》2010,26(7):18-20
本文采用五种不同方法制备了PVP稳定的Ru/Al2O3催化剂,考察了其在丙酸甲酯加氢制备丙醇反应中的催化性能.结果表明,采用金属前体、稳定剂和载体浸渍过夜,然后在磁力搅拌下用NaBH4水溶液还原制备的催化剂催化效果最好.而将金属前体还原后再负载制备的催化剂性能最差.另外,还考察了催化剂加入量、B/Ru及PVP/Ru摩尔比也对催化剂活性和选择性的影响,最佳摩尔比为:PVP/Ru=3:1及B/Ru=10:1. 相似文献
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考察了氯离子对[Pt3(CO)6[NEt4]2与Re2(CO)10分浸制备的催化剂性能的影响。发现在催化剂制备过程中加入氛离子,催化性能大大改善。初步分析了氯离子影响催化剂性能的原因。 相似文献
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Thewater gasshiftreaction (WGSR)isanimpor tantstepinmanyindustrialprocesses,includingammoni aandhydrogenproduction .Itisusuallyassistedbysev eralcatalysts ,oneofwhichisiron basedshiftcatalystwithatypicalcompositionof 74 .2 %Fe2 O3,10 .0 %Cr2 O3,0 .2 %MgO ,0 .5 %K2 Oandbalancevolatiles[1] .Obviously ,chromiaasthemainadditivecanbefoundinalmostallofiron basedhightemperaturewater gasshiftcatalysts.ThehexavalentchromiuminCrO3,thepre cursorofchromiainFe Crseriescatalysts ,isakindofveryharmfuls… 相似文献
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《浙江大学学报(A卷英文版)》2021,(2)
A co-reaction of methane with methanol over zeolite catalysts has emerged as a new approach to the long-standing challenge of methane transformation. However, the effect of catalyst acid properties on the co-reaction has been rarely studied. In this study, a series of HZSM-5 zeolites with comparable diffusion abilities and various acidities were synthesized directly through steaming with 100% water vapor at 693 K. The co-reaction of methane and methanol was subsequently evaluated. Br?nsted acidity at 0.262 mmol/g was detected to reach the maximum methane conversion of 5.42% at 673 K, which was also the odd point in the relationship between acid concentration and C4 hydrogen transfer index. Moreover, the influence of methanol feed was investigated over parent and steamed ZSM-5 catalyst, with results showing that excessive acid sites or methanol molecules reduce methane conversion. It is proposed that acid sites adsorbed with methanol molecules construct the methane activation sites. Hence, a proper design of zeolite acidity should be achieved to obtain higher methane conversion in the co-reaction process. 相似文献
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Oxidative dehydrogenation (ODH) of mono and mixed-butenes to 1,3-butadiene (BD) was conducted using individual and dual bed catalyst systems, consisting of ZnFe2O4, Co9Fe3Bi1Mo12O51 or both. The dual bed catalyst system gave improved catalytic performance. A mechanism based on synergy between the catalysts is proposed to explain the improved overall butene conversion. The proportion of the reactants differed between the catalyst beds in the dual bed system, making better use of the catalytic activity of the second bed. The existence of all butene isomers inhibited isomerization, leading to a higher proportion of ODH reactions and thus improved the conversion of butene and the yield of BD. The packing sequences and the volume ratio of the catalysts in the bed were optimized. The results indicated that the sequence with ZnFe2O4 on top and a catalyst packing ratio of between 4:6 and 6:4 led to better activity. 相似文献
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Li-hua Teng 《浙江大学学报(A卷英文版)》2008,9(9):1288-1295
Fluidized-bed reactor is a candidate for dimethyl ether (DME) synthesis from syngas because of its excellent heat removal capability. In order to improve the attrition resistance of catalyst, an amount of silica sol as binder was added to the catalyst composed of methanol synthesis component CuO/ZnO/Al2O3 and methanol dehydration component HZSM-5, which was prepared by coprecipitation and shaped by spray drying to get spherical particles. The effect of silica sol on the catalytic activity was investigated in a fixed-bed flow microreactor. Based on the experiment results, silica sol in the range of 0-20wt% had small effect on the catalytic activity. Generally, the CO conversion and DME yield decreased with the increase in concentration of silica sol, while the attrition resistance of catalysts increased with increasing silica sol, indicating that it was feasible to improve the attrition resistance without greatly sacrificing the activity of catalyst. In addition, the characterizations of catalysts were carried out using Brunauer-Emmett-Teller (BET), X-ray powder diffraction (XRD) and temperature programmed reduction (TPR). 相似文献
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Hydrogenation of ortho-nitrochlorobenzene on activated carbon supported platinum catalysts 总被引:1,自引:0,他引:1
INTRODUCTION 2,2′-dichlorohydrazobenzene (DHB) is a com-mercially important intermediate, and is convention-ally manufactured by zinc reduction of or-tho-nitrochlorobenzene (Xu, 1996). The major dis-advantage of this process is the generation of largeamounts of sludge in reduction. A single step catalytichydrogenation of ortho-nitrochlorobenzene to DHBusing supported noble metal catalyst in the presenceof aqueous sodium hydroxide medium becomes moreimportant, because it is enviro… 相似文献
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方学平 《赣南师范学院学报》1992,(Z1)
本文报道了一系列甲烷氧化偶联催化剂的制备过程及其催化性能,筛选出一个催化性能优良,又具有赣南特色的甲烷氧化偶联催化剂,其组成是Mn_2O_3—Na_3WO_4/SiO_2,代号W—34,并用XRD,BET,UV—DRS,EPR,LRS等方法对该催化剂进行了表征。结果表明,在最佳反应条件下,在W—34催化剂上甲烷转化率为36.8%,C_2烃收率达到22.9%。在该催化剂中,W是以Na_2WO_4形式存在,Mn则以Mn_2O_3形式存在,而SiO_2已由无定型构型转变成。一方石英构型。 相似文献
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为研究铂负载型催化剂时甲醛催化氧化反应的活性,采用溶胶一凝胶法制备了不同载体的铂负载型催化剂,并对催化剂进行XRD、Raman等表征,考察所制催化剂对甲醛催化氧化反应性能。结果表明:载体的性质在反应中起到重要作用,惰性载体无法促进氧的活化,其催化活性较低;对比不同比表面积的Pt/CeO2催化剂,发现比表面积为38mVg的催化剂的催化氧化性能最佳,这与催化剂的氧缺位浓度较高及较强的金属一载体间相互作用有关。 相似文献